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Exercises · 9.20

Q.What is the excess pressure inside a bubble of soap solution of radius 5.00 mm5.00\ \text{mm}, given that the surface tension of soap solution at the temperature (20 ∘C20\,^{\circ}\text{C}) is 2.50×10−2 N m−12.50 \times 10^{-2}\ \text{N m}^{-1}? If an air bubble of the same dimension were formed at depth of 40.0 cm40.0\ \text{cm} inside a container containing the soap solution (of relative density 1.201.20), what would be the pressure inside the bubble? (11 atmospheric pressure is 1.01×105 Pa1.01 \times 10^{5}\ \text{Pa}).

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For a soap bubble, there are two liquid-air interfaces, so the excess pressure is 4T/R4T/R, not 2T/R2T/R. Using T=2.50×10−2 N/mT = 2.50 \times 10^{-2}\ \text{N/m} and R=5.00 mmR = 5.00\ \text{mm}, the excess pressure is 20.0 Pa20.0\ \text{Pa}. For the submerged air bubble, the external pressure includes the atmospheric pressure plus the hydrostatic pressure from the soap solution column, and the excess pressure is 2T/R2T/R (single interface). The total pressure inside the submerged bubble is 1.06×105 Pa1.06 \times 10^{5}\ \text{Pa}.


Concept First: Why Two Interfaces Matter

The key idea here is the number of surfaces a bubble has. A soap bubble in air has two surfaces — an inner surface and an outer surface — each with its own surface tension. That doubles the excess pressure compared to a simple air bubble in liquid (which has only one interface).

The formula for excess pressure (the pressure difference across a curved interface) comes from the Young–Laplace equation:

ΔP=2TR(for one spherical interface)\Delta P = \frac{2T}{R} \quad \text{(for one spherical interface)}

For a soap bubble, there are two concentric spherical surfaces, so the total excess pressure is:

ΔPsoap bubble=4TR\Delta P_{\text{soap bubble}} = \frac{4T}{R}

For an air bubble inside the liquid (like the submerged case), there is only one interface between the air and the liquid, so:

ΔPair bubble=2TR\Delta P_{\text{air bubble}} = \frac{2T}{R}


Step-by-step Solution

1. Excess pressure in the soap bubble (in air)

Given:

  • Radius R=5.00 mm=5.00×10−3 mR = 5.00\ \text{mm} = 5.00 \times 10^{-3}\ \text{m}
  • Surface tension T=2.50×10−2 N/mT = 2.50 \times 10^{-2}\ \text{N/m}

Using the two-interface formula:

ΔP=4TR=4×2.50×10−25.00×10−3\Delta P = \frac{4T}{R} = \frac{4 \times 2.50 \times 10^{-2}}{5.00 \times 10^{-3}}

=0.1005.00×10−3=20.0 Pa= \frac{0.100}{5.00 \times 10^{-3}} = 20.0\ \text{Pa}

Tip

Notice that 20.0 Pa20.0\ \text{Pa} is tiny compared to atmospheric pressure (≈105 Pa\approx 10^5\ \text{Pa}). That’s why soap bubbles are so fragile — the internal pressure is barely above the outside.

2. Pressure inside the submerged air bubble

Now the bubble is formed inside the soap solution at a depth of 40.0 cm40.0\ \text{cm}. The external pressure on the bubble is not just atmospheric — it also includes the weight of the liquid column above it.

Step 2a: Find the external pressure at that depth

Relative density of the soap solution = 1.201.20, so its density is:

ρ=1.20×1000 kg/m3=1200 kg/m3\rho = 1.20 \times 1000\ \text{kg/m}^3 = 1200\ \text{kg/m}^3

Depth h=40.0 cm=0.400 mh = 40.0\ \text{cm} = 0.400\ \text{m}

Hydrostatic pressure:

Phydro=ρgh=1200×9.8×0.400P_{\text{hydro}} = \rho g h = 1200 \times 9.8 \times 0.400

=1200×3.92=4704 Pa= 1200 \times 3.92 = 4704\ \text{Pa} …

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