Faraday's Laws of Electrolysis
Imagine you're trying to plate a copper spoon with silver. You drop the spoon into a solution containing silver ions, connect it to a battery, and wait. How much silver actually deposits? Does it depend on how long you wait? On how strong the battery is? On what metal you're using?
Faraday's laws answer exactly these questions. They connect the invisible world of electrons flowing through a wire to the visible world of atoms depositing on a surface.
The Intuition First
Think of electrolysis as a counting problem. Each silver ion (Ag+) needs exactly one electron to become a neutral silver atom (Ag). So if you push a certain number of electrons through the circuit, you should get exactly that many silver atoms deposited.
The first law says: more charge → more mass deposited. Double the charge, double the mass. It's a direct proportionality.
The second law says: different elements need different amounts of charge per atom. A copper ion (Cu2+) needs two electrons to become neutral copper, so for the same amount of charge, you get half as many copper atoms as silver atoms.
The Precise Statements
First Law: The mass of a substance liberated at an electrode is directly proportional to the quantity of electric charge passed through the electrolyte.
m∝Qorm=ZQ
where Z is the electrochemical equivalent of the substance.
Second Law: When the same quantity of charge is passed through different electrolytes, the masses of substances liberated are proportional to their chemical equivalents (equivalent weights).
E1m1=E2m2
Here E is the equivalent weight: atomic mass divided by the number of electrons transferred per ion (n). For silver (Ag+, n=1), E=107.87 g. For copper (Cu2+, n=2), E=63.55/2=31.77 g.
The Combined Law
These two laws merge into one powerful equation:
m=FQ×E
where F is Faraday's constant — the charge carried by one mole of electrons: F=96485 coulombs per mole.
Since Q=I×t (current × time), you can write:
m=FI×t×E
This is the working formula for every electrolysis calculation in your exams.
To avoid confusion: equivalent weight E is always atomic mass divided by n (the number of electrons gained or lost per ion). For Al3+, n=3; for O2 gas (from water), each oxygen atom loses 2 electrons, but the molecule has 2 atoms, so n=4 per O2 molecule.
A Worked Example
Problem: How much copper deposits when a current of 2.0 A flows through a copper sulfate solution for 30 minutes? (Atomic mass of Cu = 63.5 g/mol, n=2)
Step 1: Find the equivalent weight.
E=263.5=31.75 g/mol
Step 2: Find total charge.
Q=I×t=2.0×(30×60)=3600 C
Step 3: Apply the combined law.
m=FQ×E=964853600×31.75=1.185 g
So about 1.2 grams of copper deposits. …