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Exercises · 9.33

Q.What do you expect the nature of hydrides is, if formed by elements of atomic numbers 15, 19, 23 and 44 with dihydrogen? Compare their behaviour towards water.

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Identify each element by its atomic number:

  • Z = 15 → Phosphorus (P), a p-block non-metal of group 15. It forms a covalent (molecular) hydride, PH3 (phosphine), an electron-rich hydride analogous to NH3. PH3 is molecular and largely unreactive/stable towards water (it does not hydrolyse readily).

  • Z = 19 → Potassium (K), an s-block alkali metal (group 1). It forms an ionic (saline) hydride, KH, containing discrete K⁺ and H⁻ ions. KH reacts violently with water, being strongly basic/reducing:

KH(s)+H2O(l)→KOH(aq)+H2(g)KH(s) + H_2O(l) \rightarrow KOH(aq) + H_2(g)

  • Z = 23 → Vanadium (V), a d-block transition metal. It forms a metallic (interstitial), non-stoichiometric hydride (VHxVH_x), where hydrogen occupies interstitial sites in the metal lattice. Such hydrides are essentially inert/unreactive towards water, retaining the metal's characteristic stability.

  • Z = 44 → Ruthenium (Ru), also a d-block transition metal. Like V, it (if it forms a hydride at all under the relevant conditions) would give a metallic/interstitial-type hydride, likewise essentially unreactive with water. …

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