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Exercises · 10.1

Q.What are the common physical and chemical features of alkali metals ?

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Physical features

  • Soft metals that can be cut with a knife; softness increases down the group.
  • Silvery-white lustre when freshly cut, tarnishes rapidly in air.
  • Low density (increases roughly down the group, with an anomaly at K), low melting and boiling points that decrease down the group.
  • Good conductors of heat and electricity.
  • Large atomic and ionic radii for their period; radii increase down the group.

Chemical features

  • Outer electronic configuration ns1^1 (one electron beyond a noble-gas core), so they are strongly electropositive and univalent (+1).
  • Very low ionisation enthalpy, decreasing down the group, making them powerful reducing agents.
  • React vigorously with water: 2M+2H2O→2MOH+H2↑2M + 2H_2O \rightarrow 2MOH + H_2\uparrow
  • React with oxygen to give oxides (Li), peroxides (Na) or superoxides (K, Rb, Cs).
  • React directly with halogens to form ionic halides, and with hydrogen to form ionic (saline) hydrides.
  • Form strongly basic hydroxides and salts that are, with few exceptions, water-soluble.
  • Impart characteristic colours to a flame (except Li being faint) due to easily excited outer electrons.
  • Dissolve in liquid ammonia to give blue, electrically-conducting solutions containing solvated (ammoniated) electrons.
✓Final answer

Common features: ns1^1 configuration, softness, low density/melting point, high reactivity from very low ionisation enthalpy, strong reducing power, and formation of univalent, mostly ionic and water-soluble compounds.

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