Exercises · 10.1
Q.What are the common physical and chemical features of alkali metals ?
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Physical features
- Soft metals that can be cut with a knife; softness increases down the group.
- Silvery-white lustre when freshly cut, tarnishes rapidly in air.
- Low density (increases roughly down the group, with an anomaly at K), low melting and boiling points that decrease down the group.
- Good conductors of heat and electricity.
- Large atomic and ionic radii for their period; radii increase down the group.
Chemical features
- Outer electronic configuration ns (one electron beyond a noble-gas core), so they are strongly electropositive and univalent (+1).
- Very low ionisation enthalpy, decreasing down the group, making them powerful reducing agents.
- React vigorously with water:
- React with oxygen to give oxides (Li), peroxides (Na) or superoxides (K, Rb, Cs).
- React directly with halogens to form ionic halides, and with hydrogen to form ionic (saline) hydrides.
- Form strongly basic hydroxides and salts that are, with few exceptions, water-soluble.
- Impart characteristic colours to a flame (except Li being faint) due to easily excited outer electrons.
- Dissolve in liquid ammonia to give blue, electrically-conducting solutions containing solvated (ammoniated) electrons.
✓Final answer
Common features: ns configuration, softness, low density/melting point, high reactivity from very low ionisation enthalpy, strong reducing power, and formation of univalent, mostly ionic and water-soluble compounds.
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