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Exercises · 6.14

Q.Giving examples, differentiate between 'roasting' and 'calcination'.

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Step 1 – Calcination

Calcination is the process of strongly heating a concentrated ore, generally below its melting point, in a limited supply of air or in its absence, primarily to remove volatile constituents such as water of crystallisation (from hydrated oxides) or carbon dioxide (from carbonates), and to make the ore porous.

Examples:

CaCO3(s)→ΔCaO(s)+CO2(g)(limestone)CaCO_3(s) \xrightarrow{\Delta} CaO(s) + CO_2(g) \quad \text{(limestone)}

Al2O3.2H2O(s)→ΔAl2O3(s)+2H2O(g)(bauxite)Al_2O_3.2H_2O(s) \xrightarrow{\Delta} Al_2O_3(s) + 2H_2O(g) \quad \text{(bauxite)}

No oxygen/air is chemically involved in these reactions — they are simple thermal decompositions.

Step 2 – Roasting

Roasting is the process of strongly heating a concentrated (usually sulphide) ore, below its melting point, in the presence of excess air/oxygen, converting the sulphide to the corresponding oxide and driving off sulphur as sulphur dioxide gas (and burning off other volatile impurities such as arsenic or antimony as their oxides).

Examples:

2ZnS(s)+3O2(g)→Δ2ZnO(s)+2SO2(g)2ZnS(s) + 3O_2(g) \xrightarrow{\Delta} 2ZnO(s) + 2SO_2(g)

2Cu2S(s)+3O2(g)→Δ2Cu2O(s)+2SO2(g)2Cu_2S(s) + 3O_2(g) \xrightarrow{\Delta} 2Cu_2O(s) + 2SO_2(g)

Step 3 – The essential difference

CalcinationRoasting
Ore typeUsually carbonate/hydrated oxideUsually sulphide
Air/O2_2Limited or absentExcess supplied

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