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Q.Explain the cleansing action of soap.

Bihar BsebBihar Board Intermediate 2022Subjective· 2mImportance★★★★★
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Soap cleans by forming micelles: its water-hating tails bury into greasy dirt while its water-loving heads face the water, so the grease is emulsified into tiny droplets that are rinsed away.

Structure of a soap molecule:

  • A soap is the sodium (or potassium) salt of a long-chain fatty acid, e.g. sodium stearate CH3(CH2)16COO⁻Na⁺.
  • It has two ends of opposite nature:
    • A long hydrocarbon chain (tail) that is non-polar and hydrophobic — it dissolves in oil/grease but not in water.
    • A polar carboxylate head (–COO⁻Na⁺) that is hydrophilic — it dissolves in water.

Mechanism of cleansing:

  1. Most dirt sticks to cloth by an oily/greasy film, which ordinary water cannot wet or remove.
  2. When soap is added to water, the molecules arrange themselves into roughly spherical clusters called micelles, with all the non-polar tails pointing inward and the polar heads pointing outward towards the water.
  3. When a greasy stain is present, the hydrophobic tails penetrate and dissolve into the grease, while the hydrophilic heads remain in the surrounding water. …

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