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Problems · Problem 1.4

Q.How many moles of methane are required to produce 22 g CO2CO_2

(g) after combustion?
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To find the moles of methane needed, first balance the combustion equation, then convert the given mass of CO2CO_2 to moles using its molar mass, and finally use the stoichiometric mole ratio from the balanced equation to find the moles of methane. The required moles of methane are 0.5 mol\boxed{0.5 \text{ mol}}.

When we talk about chemical reactions, the amounts of reactants consumed and products formed are not arbitrary. They are governed by the fundamental principle of conservation of mass, which means atoms are neither created nor destroyed in a chemical reaction. This principle is mathematically represented by a balanced chemical equation.

Stoichiometry is the branch of chemistry that deals with the quantitative relationships between reactants and products in chemical reactions. It allows us to predict how much of one substance is needed or produced given the amount of another substance involved in the reaction. The key to stoichiometry is understanding the mole concept and how it connects mass to the number of particles, and how the coefficients in a balanced equation relate the moles of different substances.

In this problem, we are given the mass of a product (CO2CO_2) and asked to find the moles of a reactant (CH4CH_4) required to produce it. The general strategy involves these steps:

  1. Write and balance the chemical equation for the reaction.
  2. Convert the given mass of the known substance into moles using its molar mass.
  3. Use the mole ratio from the balanced equation to convert moles of the known substance to moles of the unknown substance.

Let's apply this step-by-step.

  1. Write and balance the chemical equation for the combustion of methane.

    Combustion is a reaction with oxygen, typically producing carbon dioxide and water. Methane (CH4CH_4) is a hydrocarbon.

    The unbalanced equation is:

    CH4(g)+O2(g)→CO2(g)+H2O(g)CH_4(g) + O_2(g) \rightarrow CO_2(g) + H_2O(g)

    To balance it, we ensure the number of atoms of each element is the same on both sides of the equation.

    • Carbon: 1 on left, 1 on right. (Balanced)
    • Hydrogen: 4 on left, 2 on right. Place a coefficient of 2 in front of H2OH_2O on the right: CH4(g)+O2(g)→CO2(g)+2H2O(g)CH_4(g) + O_2(g) \rightarrow CO_2(g) + 2H_2O(g)
    • Oxygen: 2 on left, 22 (from CO2CO_2) +2×1+ 2 \times 1 (from 2H2O2H_2O) =4= 4 on right. Place a coefficient of 2 in front of O2O_2 on the left: CH4(g)+2O2(g)→CO2(g)+2H2O(g)CH_4(g) + 2O_2(g) \rightarrow CO_2(g) + 2H_2O(g)

    The balanced chemical equation is:

CH4(g)+2O2(g)→CO2(g)+2H2O(g)CH_4(g) + 2O_2(g) \rightarrow CO_2(g) + 2H_2O(g)

This equation tells us that 1 mole of methane reacts with 2 moles of oxygen to produce 1 mole of carbon dioxide and 2 moles of water.

2. Identify the known and unknown quantities.

* Known: Mass of CO2=22 gCO_2 = 22 \text{ g}.

* Unknown: Moles of CH4CH_4.

  1. Convert the given mass of CO2CO_2 to moles.

    To do this, we need the molar mass of CO2CO_2.

    • Molar mass of Carbon (C) ≈12.01 g/mol\approx 12.01 \text{ g/mol}
    • Molar mass of Oxygen (O) ≈16.00 g/mol\approx 16.00 \text{ g/mol}

    Molar mass of CO2=(Molar mass of C)+2×(Molar mass of O)CO_2 = (\text{Molar mass of C}) + 2 \times (\text{Molar mass of O})

    Molar mass of CO2=12.01 g/mol+2×16.00 g/molCO_2 = 12.01 \text{ g/mol} + 2 \times 16.00 \text{ g/mol}

    Molar mass of CO2=12.01 g/mol+32.00 g/molCO_2 = 12.01 \text{ g/mol} + 32.00 \text{ g/mol}

    Molar mass of CO2=44.01 g/molCO_2 = 44.01 \text{ g/mol}

    Now, convert the mass of CO2CO_2 to moles: …

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