Q.Which one of the following is the cause of acid rain?
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Start your 14-day free trial to unlock the full solution →Acid rain forms when atmospheric pollutants—primarily sulfur dioxide and nitrogen oxides—react with water vapor to produce acidic compounds. The cause is air pollution, option (d).
Acid rain is not rain that becomes acidic after falling; it is acidic before it reaches the ground. Understanding this requires looking at what happens in the atmosphere itself.
Normal rain is already slightly acidic (pH around 5.6) because atmospheric carbon dioxide dissolves in water droplets to form weak carbonic acid:
CO₂ + H₂O → H₂CO₃
But acid rain has a much lower pH—often between 4 and 4.5, sometimes even lower—because of pollutants released into the air.
How air pollution creates acid rain
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Emission of pollutants into the atmosphere
Industrial processes, coal-burning power plants, vehicle exhausts, and smelting operations release sulfur dioxide (SO₂) and nitrogen oxides (NOₓ, primarily NO and NO₂) into the air. These are gaseous pollutants that rise and disperse through the atmosphere.
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Chemical reactions in the atmosphere
Once airborne, these gases undergo oxidation and react with water vapor, oxygen, and other atmospheric chemicals:
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Sulfur dioxide forms sulfuric acid:
2SO₂ + O₂ → 2SO₃
SO₃ + H₂O → H₂SO₄
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Nitrogen oxides form nitric acid:
4NO₂ + O₂ + 2H₂O → 4HNO₃
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Incorporation into precipitation …
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