Q.Light of wavelength 488 nm is produced by an argon laser which is used in the photoelectric effect. When light from this spectral line is incident on the emitter, the stopping (cut-off) potential of photoelectrons is 0.38 V. Find the work function of the material from which the emitter is made.
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🔒 Start your 14-day free trial to unlock the full solution →Concept understanding — Maximum Kinetic Energy
Maximum Kinetic Energy – From Intuition to Precision
Kinetic energy is the energy of motion: the faster something moves, the more kinetic energy it has. In many physical situations there is a maximum possible kinetic energy a particle can reach — set either by energy conservation or by an external energy constraint.
The Precise Statement
Kmax=21mvmax2
Where:
- Kmax = maximum kinetic energy (in joules)
- m = mass of the object (in kg)
- vmax = maximum speed reached (in m/s)
This formula alone doesn't tell you why there's a maximum — the physics lies in energy conservation or in an external constraint that limits the speed.
Where Does the Maximum Come From?
1. Energy conservation (no friction)
In a closed system, total mechanical energy E=K+U is constant, so
Kmax=E−Umin
The maximum kinetic energy occurs when the potential energy U is at its minimum — for example, a falling object is fastest (and U smallest) just before it lands.
2. External constraints (e.g., the photoelectric effect)
In modern physics, electrons in a metal absorb light energy. Each photon delivers a fixed energy hf. The electron must spend part of that energy escaping the metal (the work function ϕ); the rest becomes kinetic energy:
Kmax=hf−ϕ
Here the maximum is set entirely by the photon energy — no matter how intense the light, no single electron can gain more kinetic energy than this.
A Common Mistake
Students often think "maximum kinetic energy" means the fastest speed possible in the universe. It doesn't. The "maximum" is relative to the given system — the highest value under the stated conditions (height, spring compression, photon energy, and so on), not a universal speed limit. …
Why this formula?
Maximum Kinetic Energy — Why the Formula Holds
The idea of "maximum kinetic energy" appears in two very different contexts in your syllabus: photoelectric effect (modern physics) and simple harmonic motion (oscillations). I'll cover both, because the why is different in each case.
1. In the Photoelectric Effect
The formula you must know:
Kmax=hν−ϕ
where h is Planck's constant, ν is the frequency of incident light, and ϕ is the work function of the metal.
Why this formula? It comes from Einstein's photon model and energy conservation.
A single photon carries energy E=hν. When it strikes a metal surface, it can transfer all of its energy to one electron. That electron must first overcome the binding force holding it in the metal — the minimum energy needed for this is the work function ϕ. Any leftover energy becomes the electron's kinetic energy after it escapes.
So:
Photon energy = Energy to escape + Kinetic energy of ejected electron
hν=ϕ+K
If the electron just barely escapes (with zero kinetic energy), the photon frequency is the threshold frequency ν0, where hν0=ϕ.
For a higher frequency, the maximum kinetic energy an ejected electron can have is when it absorbs the photon's full energy and loses nothing to collisions inside the metal. That gives:
Kmax=hν−ϕ
Kmax does not depend on light intensity. Intensity only increases the number of electrons, not their maximum energy. This was the key puzzle that classical physics couldn't explain.
2. In Simple Harmonic Motion (SHM)
For a particle executing SHM, the maximum kinetic energy is:
Kmax=21mω2A2
where m is mass, ω is angular frequency, and A is amplitude.
Why this formula? It follows directly from the velocity equation.
In SHM, displacement is x=Asin(ωt+ϕ). Differentiating gives velocity:
v=dtdx=Aωcos(ωt+ϕ)
The velocity is maximum when cos(ωt+ϕ)=±1, i.e., at the equilibrium position (x=0):
vmax=Aω …
Concept: Einstein's photoelectric equation, λhc=ϕ+eV0, with the stopping potential giving Kmax=eV0.
Step 1 — Photon energy. E=λhc=488 nm1240 eV⋅nm=2.54 eV.
Step 2 — Maximum KE. Kmax=eV0=0.38 eV (stopping potential 0.38 V). …
Einstein's equation gives ϕ=λhc−eV0=2.54 eV−0.38 eV=2.16 eV.
Einstein's photoelectric equation
When a photon of energy hc/λ frees an electron, part goes to overcome the work function ϕ and the rest becomes kinetic energy. The stopping potential V0 just halts the fastest electrons, so Kmax=eV0:
λhc=ϕ+eV0.
Step 1 — Photon energy of the 488 nm line
Using hc≈1240 eV⋅nm,
E=λhc=488 nm1240 eV⋅nm=2.54 eV.
Step 2 — Maximum kinetic energy
The cut-off (stopping) potential is V0=0.38 V, so
Kmax=eV0=0.38 eV. …
Method: Photoelectric Equation Approach
This problem uses Einstein's photoelectric equation, which connects the incident photon energy, the work function of the material, and the maximum kinetic energy of the emitted electrons.
Step 1: Write down the photoelectric equation
The maximum kinetic energy of photoelectrons is given by:
Kmax=hf−ϕ
where h is Planck's constant, f is the frequency of incident light, and ϕ is the work function.
The stopping potential Vs is related to Kmax by:
Kmax=eVs
where e is the electron charge.
Step 2: Convert wavelength to frequency
Given λ=488 nm=488×10−9 m, and using c=3×108 m/s:
f=λc=488×10−93×108=6.1475×1014 Hz
Step 3: Calculate the incident photon energy
Using h=6.63×10−34 J⋅s:
Ephoton=hf=(6.63×10−34)(6.1475×1014)=4.076×10−19 J
Convert to electronvolts (since 1 eV=1.6×10−19 J):
Ephoton=1.6×10−194.076×10−19=2.55 eV
Step 4: Find the maximum kinetic energy from stopping potential
Given Vs=0.38 V: …
Common Mistakes & How to Avoid Them
Mistake 1: Forgetting to convert wavelength to metres
Students often plug 488 directly into E=λhc without converting nanometres to metres. Since h is in J·s and c in m/s, λ must be in metres.
How to avoid: Always write the conversion explicitly:
λ=488 nm=488×10−9 m=4.88×10−7 m
Do this as your first step, before touching any formula.
Mistake 2: Using the wrong value of h or c
Some students use h=6.63×10−34 J⋅s but then forget to use c=3×108 m/s, or they mix up h and ℏ.
How to avoid: Write the constants clearly at the top of your solution:
h=6.63×10−34 J⋅s, c=3×108 m/s, 1 eV=1.6×10−19 J
Keep them visible throughout the calculation.
Mistake 3: Confusing stopping potential with kinetic energy
The stopping potential V0 is not the kinetic energy — it is the potential difference that stops the most energetic electrons. The maximum kinetic energy is Kmax=eV0, where e is the electron charge.
How to avoid: Remember the photoelectric equation in its two equivalent forms:
hf=ϕ+Kmax
hf=ϕ+eV0
The second form directly uses the stopping potential. Never write Kmax=V0 — that is dimensionally wrong.
Mistake 4: Forgetting to convert electron-volt answers to joules (or vice versa)
The work function is often asked in eV, but h and c give energy in joules. Students either forget to convert at all, or use the wrong conversion factor.
How to avoid: Calculate the photon energy in joules first, then convert to eV at the end if needed.
Ephoton=λhc gives joules.
1 eV=1.6×10−19 J, so divide by this to get eV.
Mistake 5: Sign errors in the photoelectric equation
Students sometimes write hf+ϕ=eV0 or hf=ϕ−eV0, both of which are incorrect.
How to avoid: The photon energy is split into two parts: work function (to free the electron) and kinetic energy (what remains). So:
hf=ϕ+eV0
ϕ=hf−eV0 …
Showing the 12 most recent of 19 on this concept.
- CBSE 2026Set A1 markMCQQ.The maximum kinetic energy of the photoelectrons varies (A) linearly with the frequency and the intensity of the incident radiation (B) linearly with the frequency and is independent of the intensity of the incident radiation (C) inversely with the frequency and is independent of the intensity of the incident radiation (D) inversely with the intensity and is independent of the frequency of the incident radiation
›Reveal solutionSolution
Einstein's photoelectric equation makes Kₘₐₓ a linear function of frequency, independent of intensity.
Einstein's photoelectric equation is:
Kmax=hν−ϕ0
where ν is the frequency of incident light and ϕ0 the work function. This is a straight line in ν (slope h), so Kmax varies linearly with frequency. Intensity only sets the number of photons (hence the photocurrent), …
- CBSE 2026Set A1 markMCQQ.The maximum velocity of an electron emitted from a metal surface becomes two times when the frequency v of the incident light is doubled. The work function of the metal is (A) 2hv/3 (B) hv/3 (C) zero (D) hv/2
›Reveal solutionSolution
Using KE ∝ v_max², doubling v_max means KE becomes 4×; solving Einstein's equation at frequency v and 2v gives φ = 2hv/3.
Einstein's photoelectric equation is
21mvmax2=hν−ϕ.
At frequency ν, maximum speed vmax:
21mvmax2=hν−ϕ.(1)
When the frequency is doubled to 2ν, the maximum speed doubles to 2vmax, so the kinetic energy becomes four times: …
- CBSE 2026Set ANNUAL1 markMCQQ.The specific charge of electron is :(a) 1.9 × 10^31 C/kg(b) 1.6 × 10^19 C/kg(c) 1.76 × 10^11 C/kg(d) 1.76 × 10^-11 C/kg
›Reveal solutionSolution
e/m = (1.6 × 10⁻¹⁹)/(9.1 × 10⁻³¹) ≈ 1.76 × 10¹¹ C/kg.
The specific charge of the electron is the ratio of its charge to its mass, e/m. Using e = 1.6 × 10⁻¹⁹ C and m = 9.1 × 10⁻³¹ kg:
…
- CBSE 2026Set ANNUAL1 markQ.Write True or False: By suitably heating, sufficient thermal energy can be imparted to the free electrons to enable them to come out of the metal.
›Reveal solutionSolution
True — this describes thermionic emission.
Free electrons in a metal are normally held inside by the surface potential barrier (the work function). If the metal is heated to a high temperature, the free electrons gain thermal energy; some acquire enough energy to overcome the work function and are emitted from the metal surface. T …
- CBSE 2025Set ANNUAL1 markMCQQ.Assertion (A): When ultraviolet light is incident on two photosensitive metals having different work functions then maximum kinetic energy of the photo electrons is greater for metal having low work function. Reason (R): Kinetic energy =21mv2(a) Both A and R are correct and R is the correct explanation of A.(b) Both A and R are correct but R is not correct explanation of A.(c) A is correct but R is incorrect.(d) A and R both are incorrect.
›Reveal solutionSolution
A is true by Einstein's photoelectric equation; R is a true but generic definition of KE that, by itself, does not explain why a lower work function gives a higher maximum photoelectron KE.
Assertion (A) is true. By Einstein's photoelectric equation, the maximum kinetic energy of an emitted photoelectron is
KEmax=hν−ϕ
where ϕ is the work function of the metal. For the same incident frequency ν, a metal with a lower work function ϕ gives a larger KEmax, so A is correct.
…
- CBSE 2025Set IMPROVEMENT1 markMCQQ.Assertion (A): Photoelectric current is zero when the stopping potential (V₀) is sufficient to repel even the most energetic (K_max) photoelectrons. Reason (R): According to Einstein's photoelectric equation, K_max = hν − ϕ₀, where hν is the energy of each quantum of radiation incident on the metal surface and ϕ₀ is the work function of the metal. Select the correct option.(a) Both A and R are correct and R is the correct explanation of A.(b) Both A and R are correct but R is not the correct explanation of A.(c) A is correct but R is incorrect.(d) Both A and R are incorrect.
›Reveal solutionSolution
Both statements are individually true, but Einstein's equation for K_max does not itself explain why the photoelectric current becomes zero at the stopping potential.
Assertion (A) is true by the very definition of the stopping potential V0: it is the minimum retarding potential that is just able to stop even the fastest (most energetic, Kmax) photoelectrons, so at V=V0 no photoelectron — however energetic — can reach the collector, and the photoelectric current drops to zero.
Reason (R) states Einstein's photoelectric equation, Kmax=hν−ϕ0, which is also true — it correctly gives the maximum kinetic energy of an emitted photoelectron in terms of the incident photon energy hν and the work function ϕ0.
…
- CBSE 2025Set ANNUAL1 markMCQQ.The energy of a photon is 18 eV and the work function of the material is 8 eV. The value of stopping potential is(a) zero(b) 8 V(c) 10 V(d) 26 V
›Reveal solutionSolution
The stopping potential (in volts) equals the maximum kinetic energy of the photoelectrons (in eV), which is the photon energy minus the work function.
Einstein's photoelectric equation:
Kmax=hν−ϕ0
where hν is the photon energy and ϕ0 is the work function. Given hν=18 eV and ϕ0=8 eV:
…
- CBSE 2025Set ANNUAL1 markMCQQ.The maximum kinetic energy of the photoelectrons depends only on :(a) incident angle.(b) frequency.(c) pressure.(d) potential.
›Reveal solutionSolution
By Einstein's photoelectric equation, KEmax=hν−ϕ0, so for a given metal (fixed work function ϕ0) the maximum KE depends only on the frequency ν of incident light, not on its intensity.
Einstein's photoelectric equation is
KEmax=hν−ϕ0
where h is Planck's constant, ν is the frequency of incident radiation, and ϕ0 is the work function of the metal (a fixed property of the material). Increasing the intensity of light increases the number of photoelectrons emitted (photocurrent) but not the maximum kinetic energy o …
- CBSE 2025Set ANNUAL1 markMCQQ.The maximum kinetic energy of photoelectrons emitted from a metal surface when photons of energy 5.6 eV fall on it, is 4eV. The stopping potential in volts is –(a) 1.6 V(b) 3.2V(c) 4V(d) 5.6V
›Reveal solutionSolution
Stopping potential V0=KEmax/e, and KEmax is already given directly as 4 eV.
The stopping potential is defined by eV0=KEmax. Here KEmax is given directly as 4eV (not needing to be computed from the photon energy and work function, both of which are alread …
- CBSE 2025Set ANNUAL1 markMCQQ.In photoelectric emission, a radiation whose frequency is 4 times threshold frequency of a certain metal is incident on the metal. Then, the maximum possible velocity of the emitted electron will be :(a) 2mhν0(b) mhν0(c) 2mhν0(d) m6hν0
›Reveal solutionSolution
With incident frequency 4ν0, Einstein's photoelectric equation gives KEmax=3hν0, so vmax=6hν0/m.
Working
Einstein's photoelectric equation: KEmax=hν−hν0.
Given ν=4ν0:
KEmax=h(4u0)−hu0=3hu0
Since KEmax=21mvmax2: …
- CBSE 2024Set ANNUAL1 markMCQQ.The maximum kinetic energy of a photo electron emitted from a metal is 1.8 eV. The value of stopping potential (cut-off voltage) will be -(a) 3.6 V(b) 2.0 V(c) 1.8 V(d) 0.9 V
›Reveal solutionSolution
The stopping potential V₀ is defined by eV₀ = KE_max, so measuring KE_max in electron-volts directly gives V₀ in volts.
The stopping potential V0 is the retarding potential just sufficient to stop even the fastest photoelectrons, defined by:
eV0=KEmax
Here KEmax=1.8 eV, i.e. KEmax=1.8e (in joules, using the electron-volt definition). Substituting:
…
- CBSE 2024Set ANNUAL1 markMCQQ.Photons of energies 1eV and 2eV are successively incident on a metallic surface of work function 0.5 eV. The ratio of kinetic energy of most energetic photoelectrons in the two cases will be -(a) 1:2(b) 1:3(c) 1:1(d) 1:4
›Reveal solutionSolution
Einstein's photoelectric equation gives KEmax=Ephoton−ϕ; subtract the same work function from each photon energy and take the ratio.
Work function ϕ=0.5 eV.
KE1=1−0.5=0.5 eV …
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