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Q.What happens when (write only chemical equation)? [1+1+1+1+1=5]

(a) Carboxylic acid reacts with alcohol
(b) The reduction of acetaldehyde occurs in the presence of zinc amalgam/HCl
(c) Toluene reacts with chromyl chloride in the presence of CS2
(d) Acetic acid reacts with Na metal
(e) NaOH and I2 react with acetone OR Explain the following (write only chemical equation):
(a) Stephen's reaction
(b) Aldol condensation
(c) Cannizzaro reaction
(d) Gattermann-Koch reaction
(e) Friedel-Crafts reaction
Chhattisgarh CgbseCGBSE Intermediate Board 2022Subjective· 5mImportance★★★★★
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Five classic carbonyl/carboxylic-acid reactions: esterification, Clemmensen reduction, Etard reaction, acid–metal reaction, and the iodoform reaction.

  1. Carboxylic acid + alcohol (Fischer esterification): RCOOH+R′OH→Δconc. H2SO4RCOOR′+H2ORCOOH + R'OH \xrightarrow[\Delta]{conc.\ H_2SO_4} RCOOR' + H_2O
  2. Reduction of acetaldehyde with zinc amalgam/HCl (Clemmensen reduction — carbonyl fully reduced to CH2): CH3CHO→Zn(Hg)/conc. HClCH3CH3 (ethane)+H2OCH_3CHO \xrightarrow{Zn(Hg)/conc.\ HCl} CH_3CH_3\ (ethane) + H_2O
  3. Toluene + chromyl chloride in CS2, then hydrolysis (Etard reaction — gives benzaldehyde): C6H5CH3→CrO2Cl2, CS2(chromium complex)→H3O+C6H5CHOC_6H_5CH_3 \xrightarrow{CrO_2Cl_2,\ CS_2} (chromium\ complex) \xrightarrow{H_3O^+} C_6H_5CHO
  4. Acetic acid + sodium metal: 2CH3COOH+2Na→2CH3COONa+H2↑2CH_3COOH + 2Na \rightarrow 2CH_3COONa + H_2\uparrow …

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