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Question of 87

Q.Ethanoyl chloride + Ethanol -> A. 'A' is

(a) Methyl ethanoate
(b) Ethyl ethanoate
(c) Ethyl methanoate
(d) None of these
Jharkhand JacJAC Intermediate Board 2018MCQ· 1mImportance★★★★★
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Acid chlorides are highly reactive acylating agents; reacting ethanoyl chloride with ethanol replaces the -Cl with -OC2H5, giving the ester ethyl ethanoate.

CH3COCl (ethanoyl/acetyl chloride) + C2H5OH (ethanol) -> CH3COOC2H5 + HCl.

MECHANISM (brief): The alcohol's oxygen (nucleophile) attacks the electrophilic carbonyl carbon of the acid chloride, displacing chloride ion; this is a nucleophilic acyl substitution, and acid chlorides undergo it very readily (much faster than the corresponding acid + alcohol, which needs …

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