Question of 87
Q.Ethanoyl chloride + Ethanol -> A. 'A' is
(a) Methyl ethanoate
(b) Ethyl ethanoate
(c) Ethyl methanoate
(d) None of these
Jharkhand JacJAC Intermediate Board 2018MCQ· 1mImportance★★★★★
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Start your 14-day free trial to unlock the full solution →Acid chlorides are highly reactive acylating agents; reacting ethanoyl chloride with ethanol replaces the -Cl with -OC2H5, giving the ester ethyl ethanoate.
CH3COCl (ethanoyl/acetyl chloride) + C2H5OH (ethanol) -> CH3COOC2H5 + HCl.
MECHANISM (brief): The alcohol's oxygen (nucleophile) attacks the electrophilic carbonyl carbon of the acid chloride, displacing chloride ion; this is a nucleophilic acyl substitution, and acid chlorides undergo it very readily (much faster than the corresponding acid + alcohol, which needs …
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