Skip to content
Question of 87

Q.(a) How is acetic acid prepared from methyl magnesium bromide? What happens when it reacts with

(i) Na2CO3 and
(ii) C2H5OH in the presence of conc. H2SO4? (2+2+2)
(b) Write the IUPAC name of CH3-CH(CH3)-COOH. (1)
Odisha ChseOdisha CHSE +2 Science Board Exam 2023Subjective· 7mImportance★★★★★
0% · 0/87 Questions
🔒 Locked · start free trial →

You're viewing a preview — the full solution, concept, methods & PYQ mapping are locked.

Start your 14-day free trial to unlock the full solution →

The Grignard reagent CH3MgBr reacts with CO2 (dry ice) and then acidic hydrolysis gives acetic acid; acetic acid shows the typical carboxylic-acid reactions of effervescence with carbonate and ester formation with an alcohol.

(a) Preparation of acetic acid from methyl magnesium bromide:

Methylmagnesium bromide reacts with carbon dioxide (usually passed over crushed dry ice) to form the magnesium salt of the acid, which on hydrolysis with dilute acid gives acetic acid:

CH3MgBr + CO2 -> CH3-C(=O)-O-MgBr --(H3O+ / dilute HCl)--> CH3COOH (acetic acid) + Mg(OH)Br

(i) Reaction with Na2CO3: being an acid stronger than carbonic acid, acetic acid decomposes sodium carbonate with brisk effervescence of CO2 gas - this is in fact a standard chemical test for the -COOH group:

2 CH3COOH + Na2CO3 -> 2 CH3COONa + H2O + CO2 (gas evolved)

…

Unlock everything free for 14 days

  • Full step-by-step solutions
  • Concept-first explanations
  • Methods, shortcuts & mistakes
  • PYQ mapping + timed mock tests

Full access for 14 days. No credit card required.