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Q.Write the definition of electromotive force of a cell and relate it to its internal resistance.

Chhattisgarh CgbseCGBSE Intermediate Board 2021Subjective· 3mImportance★★★★★
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EMF is the maximum potential the cell can supply (measured at open circuit); when current flows, some of it is used up driving charge through the cell's own internal resistance, so ε=V+Ir\varepsilon = V + Ir.

Electromotive Force (EMF) of a cell, denoted ε\varepsilon, is defined as the work done by the cell in moving a unit positive charge once around the complete circuit (including through the cell itself). Equivalently, it is the potential difference across the terminals of the cell when no current is being drawn (open circuit).

Relation to internal resistance: A real cell has some internal resistance rr due to the electrolyte/materials inside it. When the cell drives a current II through an external resistance RR, some of the EMF is used to overcome the potential drop across this internal resistance:

ε=IR+Ir=V+Ir\varepsilon = IR + Ir = V + Ir

where V=IRV = IR is the terminal potential difference (voltage available to the external circuit). Rearranging: …

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