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Exercises · 5.6

Q.The drain cleaner, Drainex contains small bits of aluminum which react with caustic soda to produce dihydrogen. What volume of dihydrogen at 20 °C and one bar will be released when 0.15g of aluminum reacts?

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Step 1 – Write the balanced equation

2Al(s)+2NaOH(aq)+2H2O(l)⟶2NaAlO2(aq)+3H2(g)2\text{Al}(s) + 2\text{NaOH}(aq) + 2\text{H}_2\text{O}(l) \longrightarrow 2\text{NaAlO}_2(aq) + 3\text{H}_2(g)

Step 2 – Moles of aluminium

n(Al)=0.15 g27 g mol−1=5.556×10−3 moln(\text{Al}) = \frac{0.15\ \text{g}}{27\ \text{g mol}^{-1}} = 5.556\times10^{-3}\ \text{mol}

Step 3 – Moles of H2_2 produced (stoichiometry: 2 Al → 3 H2_2)

n(H2)=32×n(Al)=32×5.556×10−3=8.333×10−3 moln(\text{H}_2) = \frac{3}{2}\times n(\text{Al}) = \frac{3}{2}\times 5.556\times10^{-3} = 8.333\times10^{-3}\ \text{mol}

Step 4 – Apply the ideal gas equation to find volume …

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