Q.If the concentration of glucose (C6H12O6) in blood is 0.9 g L−1, what will be the molarity of glucose in blood?
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Molality: The Concentration That Ignores Temperature
Imagine you're making a cup of sweet tea. You add sugar to hot water, stir, and taste. If you let the tea cool to room temperature, the amount of sugar hasn't changed — but the volume of the liquid has shrunk slightly. If you measured concentration as "grams of sugar per litre of solution," that number would change just because the temperature changed. That's annoying if you're a chemist who needs a reliable, temperature-independent way to describe how much solute is present.
Molality was invented to solve exactly this problem.
The Intuition
Instead of measuring the volume of the solution (which expands and contracts with temperature), molality measures the mass of the solvent. Mass doesn't change with temperature. So molality gives you a concentration that stays the same whether your solution is hot or cold.
Think of it this way:
- Molarity = moles of solute per litre of solution (temperature-sensitive)
- Molality = moles of solute per kilogram of solvent (temperature-independent)
The solvent is the substance doing the dissolving — usually water. The solute is what gets dissolved — sugar, salt, etc.
The Precise Definition
Molality (m)=kilograms of solventmoles of solute
The symbol for molality is a lowercase m (not to be confused with M for molarity).
Key points to remember:
- The denominator is solvent mass, not solution mass
- The unit is mol/kg (often written as simply "m")
- It is independent of temperature because mass doesn't change with temperature
Worked Example
Problem: 36 g of glucose (C6H12O6, molar mass = 180 g/mol) is dissolved in 500 g of water. Calculate the molality of the solution.
Step 1: Find moles of solute
Moles of glucose=180 g/mol36 g=0.2 mol
Step 2: Convert solvent mass to kilograms
500 g=0.5 kg
Step 3: Apply the formula
m=0.5 kg0.2 mol=0.4 m
The answer is 0.4 m (or 0.4 mol/kg). Notice we used the mass of water (500 g), not the mass of the solution (which would be 536 g).
Common Mistake to Avoid
Do not use the mass of the solution in the denominator. The formula specifically asks for the mass of the solvent alone. If the problem gives you the total mass of the solution, subtract the mass of the solute to find the solvent mass.
When Do You Use Molality?
Molality is the star in two important situations: …
Why this formula?
Molality Calculation: Why the Formula Works
Molality is a measure of concentration that is temperature-independent — this is its key advantage over molarity. Let's understand why the formula takes the form it does.
The Definition First
Molality (m) is defined as:
m=mass of solvent in kgmoles of solute
The unit is mol/kg, often written as m (e.g., 0.5 m glucose solution).
Why Mass of Solvent, Not Solution?
This is the critical conceptual point.
The Reasoning
- Molarity uses volume of solution → volume changes with temperature (expansion/contraction). So molarity changes with temperature.
- Molality uses mass of solvent → mass is invariant with temperature. So molality remains constant regardless of temperature changes.
Key insight: By using the solvent's mass (not the solution's volume), we eliminate temperature dependence. This is why molality is preferred for colligative properties (boiling point elevation, freezing point depression) — these properties depend on the number of solute particles, not on temperature.
Deriving the Formula Step-by-Step
Step 1: Moles of Solute
If you have wsolute grams of solute with molar mass Msolute (g/mol):
moles of solute=Msolutewsolute
Step 2: Mass of Solvent in kg
If the solvent mass is Wsolvent grams:
mass of solvent in kg=1000Wsolvent
Step 3: Putting It Together
m=1000WsolventMsolutewsolute
Simplifying:
m=Msolute×Wsolventwsolute×1000
The Final Formula (Exam-Ready)
m=Msolute×Wsolventwsolute×1000
Where:
- wsolute = mass of solute in grams
- Msolute = molar mass of solute in g/mol
- Wsolvent = mass of solvent in grams
Why the ×1000 Factor? …
The key idea is molarity calculation: molarity (M) = moles of solute per litre of solution.
Step 1: Find the molar mass of glucose (C6H12O6).
6×12+12×1+6×16=72+12+96=180 g mol−1.
Step 2: Convert the given concentration to moles per litre.
Moles of glucose in 1 L = 180 g mol−10.9 g=0.005 mol. …
Molarity is moles per litre. Given 0.9 g L−1 of glucose (molar mass 180 g mol−1), the molarity is 0.9/180=0.005 M. The correct option is (iii).
The question asks for molarity, not molality — a common point of confusion. Molarity (M) is defined as the number of moles of solute per litre of solution. Here, the concentration is already given in grams per litre (g L−1), which is a mass concentration. Converting that to molarity is straightforward: divide by the molar mass of glucose.
Glucose has the formula C6H12O6. Let’s calculate its molar mass quickly:
- Carbon: 6×12=72
- Hydrogen: 12×1=12
- Oxygen: 6×16=96
- Total: 72+12+96=180 g mol−1
Now, the given mass concentration is 0.9 g L−1. That means every litre of blood contains 0.9 grams of glucose.
-
Find moles of glucose per litre
Moles = mass / molar mass = 0.9 g/180 g mol−1=0.005 mol.
-
Molarity is moles per litre
Since we already have the mass per litre, the moles per litre is exactly 0.005 mol L−1, which is 0.005 M. …
Method: Molarity from Mass Concentration
Concept first: Molarity (M) tells us the number of moles of solute per litre of solution.
We are given mass per litre (0.9 g L−1). To convert to moles per litre, we need the molar mass of glucose.
Steps
Step 1 — Find molar mass of glucose (C6H12O6)
- Carbon: 6×12=72
- Hydrogen: 12×1=12
- Oxygen: 6×16=96
Molar mass = 72+12+96=180 g mol−1
Step 2 — Convert mass concentration to molarity
Molarity (M) = molar mass (g/mol)mass per litre (g/L) …
Step 1: Understand what is being asked
We are given:
- Solute: glucose, C6H12O6
- Concentration: 0.9 g L−1 (mass per volume)
- We need: Molarity (moles per litre)
Molarity =volume of solution in litresmoles of solute
So the first step is to convert grams per litre into moles per litre.
Step 2: Calculate molar mass of glucose
Glucose: C6H12O6
- Carbon: 6×12=72
- Hydrogen: 12×1=12
- Oxygen: 6×16=96
Molar mass =72+12+96=180 g mol−1
Step 3: Convert given concentration to molarity
Given: 0.9 g L−1
Moles per litre =1800.9=0.005 mol L−1
So molarity =0.005 M
Correct answer: (iii) 0.005 M
Common Mistakes & How to Avoid Them
✗ Mistake 1: Confusing molality with molarity
- What students do: They try to use mass of solvent or density, which is not given.
- Why it’s wrong: Molarity uses volume of solution (given as 1 L here). Molality uses mass of solvent (in kg).
- How to avoid: Read the unit carefully — g L−1 is a mass/volume concentration, directly convertible to molarity.
✗ Mistake 2: Forgetting to convert grams to moles
- What students do: They take 0.9 g L−1 and think it’s already moles.
- Why it’s wrong: Molarity is moles per litre, not grams per litre.
- How to avoid: Always ask: “Is this in grams or moles?” If grams, divide by molar mass.
✗ Mistake 3: Incorrect molar mass of glucose
- What students do: Use C6H12O6 as 6+12+6=24 or forget to multiply atomic masses.
- Why it’s wrong: Each element’s atomic mass must be multiplied by its subscript.
- How to avoid: Write out the calculation step-by-step: 6×12=72, 12×1=12, 6×16=96, then sum.
✗ Mistake 4: Decimal error in division
- What students do: 0.9÷180=0.005 but they write 0.05 or 0.5.
- Why it’s wrong: Misplacing the decimal changes the answer by a factor of 10 or 100. …
- COMEDK 2025Set 2025-A1 markMCQQ.Lead storage battery contains 4.25MH2SO4 which has a density of 1.24 g/ml. Calculate the molality of aqueous solution of H2SO4. (A) 6.264 (B) 3.427 (C) 5.161 (D) 4.108
›Reveal solutionSolution
Molality is moles of solute per kilogram of solvent. Given molarity and density, we find the mass of 1 L of solution, subtract the mass of H₂SO₄ to get solvent mass, then compute molality. The result is 5.161 m, so option (C) is correct.
Concept & Intuition
Molality (m) depends on the mass of solvent, not the volume of solution. Molarity (M) gives moles per liter of solution, but the solvent mass is hidden inside the density. The trick: take exactly 1 liter of solution, find its total mass from density, subtract the mass of H₂SO₄ (from moles × molar mass), and you have the solvent mass in kg. Then molality = moles / kg solvent.
Step-by-step solution
-
Interpret the given data
- Molarity of H₂SO₄ = 4.25 M → 4.25 moles per liter of solution.
- Density of solution = 1.24 g/mL = 1240 g/L (since 1 mL = 1 g water equivalent, but here it’s the whole solution).
- Molar mass of H₂SO₄ = 2(1.008) + 32.06 + 4(16.00) = 98.08 g/mol (we’ll use 98.08).
-
Mass of 1 liter of solution
Mass of solution=1.24 mLg×1000 mL=1240 g
- Mass of H₂SO₄ in 1 liter
Moles of H₂SO₄=4.25 mol
Mass of H₂SO₄=4.25×98.08=416.84 g
- Mass of solvent (water) in 1 liter
-
- COMEDK 2025Set 2025-E1 markMCQQ.The mole fraction of an unknown solute in 1560 g of Benzene is 0.5 . What is the molality of the solution? (M. M of Benzene:78 amu) (A) 12.8 (B) 10.3 (C) 3.25 (D) 16.9
›Reveal solutionSolution
The key idea is to use the definition of mole fraction to find the moles of solute, then divide by the mass of solvent in kg. The molality is 12.8 m, so the correct option is (A).
Concept and Intuition
Mole fraction tells us the ratio of moles of one component to the total moles in the mixture. Here, the mole fraction of solute is 0.5, meaning the solute and solvent have equal moles. Since we know the mass of benzene (solvent) and its molar mass, we can find the moles of benzene, then the moles of solute, and finally the molality (moles of solute per kg of solvent). The trap is forgetting to convert grams to kilograms for molality.
Step-by-step solution
- Find moles of benzene (solvent) Mass of benzene = 1560 g Molar mass of benzene (C₆H₆) = 78 g/mol
nbenzene=78 g/mol1560 g=20 mol
- Use mole fraction to find moles of solute Mole fraction of solute, Xsolute=0.5 By definition:
Xsolute=nsolute+nbenzenensolute
Substitute known values:
0.5=nsolute+20nsolute
Multiply both sides by nsolute+20:
0.5(nsolute+20)=nsolute
0.5nsolute+10=nsolute
10=0.5nsolute⇒nsolute=20 mol
- Calculate molality …
- COMEDK 2024Set 2024-E1 markMCQQ.Sulphuric acid used in Lead Storage battery has a concentration of 4.5 M and a density of 1.28 g/ ml. The molality of the acid is __________. (A) 4.012 (B) 2.568 (C) 5.364 (D) 3.516
›Reveal solutionSolution
Take 1 L of solution: it holds 4.5 mol H2SO4 in (1280−441)=839 g water, giving molality ≈5.36 m.
Molar mass of H2SO4=98 g/mol. Consider 1 L of the 4.5 M solution.
Mass of solution:
1.28 g/mL×1000 mL=1280 g
Mass of H2SO4:
4.5 mol×98 g/mol=441 g …
- COMEDK 2023Set 2023-E1 markMCQQ.What is the mole fraction of solute in a 5 m aqueous solution? (A) 0.038 (B) 0.593 (C) 0.082 (D) 0.751
›Reveal solutionSolution
Mole fraction of solute: x_solute = 5 / (5 + 55.55) = 5 / 60.55 = 0.0826 ~ 0.082
Concept: molality m = moles of solute per 1 kg (1000 g) of solvent. Convert to mole fraction.
Basis: 1000 g of water.
moles of solute = 5 mol
moles of water = 1000 / 18 = 55.55 mol …
- COMEDK 2021Set 20211 markMCQQ.What would be the molarity of one litre solution of 22.2 g of CaCl2 ? (A) 0.2 M (B) 0.4 M (C) 0.6 M (D) 0.8 M
›Reveal solutionSolution
Molarity = 0.2 / 1 = 0.2 M
Concept: Molarity = moles of solute / volume of solution in litres.
Molar mass of CaCl2 = 40 + 2(35.5) = 111 g/mol
Moles = 22.2 / 111 = 0.2 mol
Volume = 1 L …
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