Q.An ideal gas undergoes four different processes starting from the same initial state, drawn on a P-V diagram (pressure P vertical, volume V horizontal). The four processes are, in some order, adiabatic, isothermal, isobaric and isochoric. Starting from the common initial point (upper-left region): curve 4 is the flat, topmost curve along which the pressure barely changes as the volume increases; curve 3 falls off below it as the volume increases; curve 2 is the lowest of the three expansion curves, falling most steeply as the volume increases; and curve 1 is a vertical line dropping straight down from the initial state (volume unchanged, pressure decreasing). Which numbered curve is the adiabatic process?
Concept understanding — Adiabatic Compression Factor
Adiabatic Compression Factor: From Intuition to Precision
Imagine you pump air into a bicycle tyre. The pump gets noticeably warm. That warmth isn't coming from outside — it's generated inside the air you're compressing. Why? Because you're doing work on the gas, and since the compression happens too fast for heat to escape, all that work stays inside as internal energy, raising the temperature.
This is the core idea: adiabatic means "no heat exchange with the surroundings." When you compress a gas adiabatically, its temperature rises. The adiabatic compression factor is the ratio that tells you how much the temperature rises for a given compression.
The Intuition First
Think of a gas as a swarm of tiny, fast-moving particles. When you push a piston in, you're moving the wall toward the particles. Each time a particle bounces off the approaching wall, it rebounds with a higher speed than it had — like a tennis ball hit by a moving racket. Faster particles mean higher temperature.
If the compression is slow enough that heat can leak out (isothermal), the temperature stays constant. But if it's fast (adiabatic), the temperature climbs. The adiabatic compression factor captures exactly this: the ratio of final temperature to initial temperature when a gas is compressed without heat loss.
The Precise Statement
For an ideal gas undergoing a reversible adiabatic process, the relationship between temperature (T) and volume (V) is:
TVγ−1=constant
where γ (gamma) is the adiabatic index — the ratio of specific heats: γ=CvCp.
If you compress from volume V1 to V2 (so V2<V1), the temperature changes from T1 to T2 according to:
T2=T1(V2V1)γ−1
The factor (V2V1)γ−1 is the adiabatic compression factor for temperature. Since V1/V2>1 and γ−1>0, this factor is always greater than 1 — confirming that temperature rises.
Adiabatic compression factor (temperature)=(V2V1)γ−1
You can also express it in terms of pressure. Using PVγ=constant, you get:
T2=T1(P1P2)γγ−1
Here (P1P2)γγ−1 is the pressure-based version.
What γ Means
γ depends on the number of degrees of freedom of the gas molecule:
| Gas type | Degrees of freedom | γ | Example |
|---|---|---|---|
| Monatomic | 3 (translation only) | 5/3 ≈ 1.67 | He, Ar |
| Diatomic / linear triatomic (rigid) | 5 (3 translation + 2 rotation) | 7/5 = 1.40 | N₂, O₂; CO₂ (theoretical) |
| Non-linear triatomic | 6 (3 translation + 3 rotation) | 4/3 ≈ 1.33 | H₂O vapour |
A higher γ means the temperature rises more sharply for the same compression. Monatomic gases heat up the most — they have only translational motion to store energy, so all the work of compression goes into raising temperature.
CO₂ is a linear triatomic molecule (O=C=O), so the rigid-rotor kinetic-theory model actually predicts the same γ as a diatomic gas (7/5 = 1.40), not 4/3. The 4/3 value belongs to non-linear triatomic molecules such as water vapour, which have a genuine third rotational degree of freedom. In practice, real CO₂ shows γ≈1.30 because its bending vibrational mode is active at ordinary temperatures — a correction beyond this simple rigid-molecule model. Don't memorise "triatomic = 4/3" as a blanket rule; it only holds for non-linear triatomics.
Also, do not confuse the adiabatic compression factor with the plain compression ratio of an engine. The compression ratio is V1/V2 — a purely geometric ratio. The adiabatic compression factor includes γ and tells you the thermal effect of that compression.
A Quick Example
Air at 300 K is compressed adiabatically to one-tenth its volume. For air (mostly diatomic), γ=1.4.
T2=300×(10)1.4−1=300×100.4
100.4≈2.51, so T2≈753 K (about 480°C). That's why diesel engines don't need spark plugs — the adiabatic compression of air alone raises its temperature enough to ignite the injected fuel.
The Big Picture
The adiabatic compression factor isn't a separate formula to memorise — it's the temperature multiplier that emerges naturally from the adiabatic condition TVγ−1=constant. Whenever you see "adiabatic compression" in an exam, immediately think: temperature rises, and the rise is governed by γ (fixed by the gas's degrees of freedom) and the volume (or pressure) ratio. That's the entire concept.
This topic is commonly searched as "Adiabatic Compression Factor 11 physics important questions" or "Adiabatic Compression Factor formula and examples", and it maps cleanly onto the Class 11 Physics portion of the NCERT/CBSE syllabus. Because adiabatic compression factor shows up repeatedly in JEE Main, NEET and state engineering/medical entrance exams, mastering the underlying idea (not just the formula) is genuinely worth the extra time.
On a P-V diagram the adiabatic (PVγ=const) falls more steeply than the isothermal (PV=const) but is not vertical. Among the three curves that fall as the volume increases, the steepest is curve 2.
The horizontal curve 4 is isobaric, the vertical curve 1 is isochoric, and of the remaining two, curve 2 (steeper) is adiabatic while curve 3 is isothermal.
Option (C) — curve 2 is the adiabatic process.
The slope of a process on a P-V diagram tells you what it is: horizontal (slope 0) is isobaric, vertical is isochoric, and between them the adiabatic is steeper than the isothermal. Curve 4 is isobaric, curve 1 isochoric, curve 3 isothermal and curve 2 — the steepest of the expansion curves — is adiabatic.
Concept
For each process the slope dVdP at the common starting state is:
- Isobaric (P=const): dVdP=0 → horizontal line.
- Isothermal (PV=const): dVdP=−VP.
- Adiabatic (PVγ=const): dVdP=−γVP, which is γ times steeper than the isothermal (since γ>1).
- Isochoric (V=const): vertical line, slope −∞.
Ranking the curves
Starting from the same point, order of steepness (least to most negative) is: isobaric (flat) < isothermal < adiabatic < isochoric (vertical). Matching to the diagram:
- Curve 4 (flat, top) = isobaric.
- Curve 3 (moderate fall) = isothermal.
- Curve 2 (steepest fall) = adiabatic.
- Curve 1 (vertical) = isochoric.
Distractors: (A) 4 is isobaric, (D) 1 is isochoric, (B) 3 is isothermal — all wrong because the adiabatic must lie between the isothermal and the vertical isochoric.
Option (C) — curve 2 is the adiabatic process.
Rather than computing slopes, reason physically about why the adiabatic curve must fall between the isothermal and isochoric ones: in an isothermal expansion, pressure drops only because volume increases (heat flows in to hold T fixed); in an adiabatic expansion, no heat flows in at all, so the gas must cool as it does work — and that cooling makes the pressure drop for a second, independent reason. Hence the adiabatic curve always falls faster than the isothermal one from the same starting point. This picture — 'adiabatic loses both volume-room and heat-compensation, isothermal loses only volume-room' — lets you rank the curves by eye without writing a single derivative.
- COMEDK 2025Set 2025-A1 markMCQQ.A monoatomic ideal gas, initially at temperature T1, is enclosed in a cylinder fitted with a frictionless piston. The gas is allowed to expand adiabatically to a temperature T2 by releasing the piston suddenly. If L and 2L are the lengths of the gas column before and after expansion respectively, then T2T1 is (A) 23/2 (B) 22/3 (C) (21)2/3 (D) (21)3/2
›Reveal solutionSolution
For an adiabatic process in a monoatomic ideal gas, the relation TVγ−1=constant applies. Here volume doubles, so T2T1=22/3, which corresponds to option (B).
The key concept is the adiabatic process for an ideal gas. “Adiabatic” means no heat exchange with the surroundings. When the piston is released suddenly, the gas expands quickly, so there’s no time for heat to flow — the process is adiabatic. For an ideal gas undergoing a reversible adiabatic process (and here the sudden release approximates a free expansion, but the problem treats it as a quasi-static adiabatic expansion because the piston is frictionless and the gas does work), the relation between temperature and volume is:
TVγ−1=constant
where γ=CvCp. For a monoatomic ideal gas, γ=35.
Now, step by step:
- Identify the volume change. The initial length of the gas column is L, and the final length is 2L. Since the cylinder has a constant cross-sectional area, volume is proportional to length. So:
V1∝L,V2∝2L⇒V1V2=2
- Apply the adiabatic relation. For an adiabatic process:
T1V1γ−1=T2V2γ−1
Rearranging:
T2T1=(V1V2)γ−1
- Substitute the values. γ=35, so γ−1=32. And V1V2=2. Thus:
T2T1=22/3
- Match with the options. This is exactly option (B).
Watch outA common mistake is to use PVγ=constant and then try to relate temperature via the ideal gas law, but that leads to the same result if done correctly. Another pitfall is confusing γ for diatomic gases (7/5) — here it’s monoatomic, so γ=5/3.
TipRemember the shortcut: For an adiabatic process, T∝V−(γ−1). If volume doubles, temperature drops by a factor of 2γ−1. For monoatomic gas, that’s 22/3.
✓Final answerThe correct option is (B).
ANSWER: B
- COMEDK 2025Set 2025-E1 markMCQQ.A given volume of gas at NTP is allowed to expand 6 times of its original volume, first under isothermal condition and then under adiabatic condition. Which of the given statement is correct? [Given cvcp=γ=1.4 ] (A) The final pressure after the adiabatic expansion is 1.4 times greater than the final pressure after the isothermal expansion. (B) The final temperature after the adiabatic expansion is 1.4 times less than the final temperature after the isothermal expansion. (C) Pressure remains same in both adiabatic and isothermal expansion (D) The final pressure after the adiabatic expansion is less than the final pressure after the isothermal expansion.
›Reveal solutionSolution
For a gas expanding to six times its volume, the adiabatic final pressure is much lower than the isothermal final pressure because adiabatic expansion also cools the gas, reducing pressure further. The correct option is (D).
Concept & Intuition
The key difference between isothermal and adiabatic expansions lies in temperature.
- Isothermal: Temperature stays constant. Pressure drops only because volume increases (Boyle’s Law: P∝1/V).
- Adiabatic: No heat exchange. The gas does work using its internal energy, so its temperature falls. Pressure drops for two reasons: volume increase and temperature decrease.
Thus, for the same volume increase, the final pressure after adiabatic expansion is always lower than after isothermal expansion. This is a classic result for an ideal gas.
Step-by-step reasoning
- Isothermal expansion For an ideal gas at constant temperature:
P1V1=P2V2
Initial volume V1=V, final volume V2=6V.
Initial pressure at NTP is P1=1 atm (say).
Piso=V2P1V1=6V1⋅V=61 atm
- Adiabatic expansion For a reversible adiabatic process:
P1V1γ=P2V2γ
with γ=1.4.
Padia=P1(V2V1)γ=1⋅(61)1.4
Compute: (61)1.4=6−1.4.
Since 61.4>61=6, we have 6−1.4<61.
Numerically: 61.4=e1.4ln6≈e1.4×1.7918=e2.5085≈12.3.
So Padia≈12.31≈0.0813 atm, while Piso=0.1667 atm.
Clearly, Padia<Piso.
- Check the options
- (A) says adiabatic pressure is 1.4 times greater — false (it’s smaller).
- (B) says final temperature after adiabatic is 1.4 times less — temperature does drop, but not by exactly a factor of 1.4; also the question asks about pressure comparison.
- (C) says pressure remains same — false.
- (D) says final pressure after adiabatic is less than after isothermal — true.
Watch outA common mistake is to forget that in adiabatic expansion the temperature drops, so the pressure falls faster than in isothermal expansion. Many students incorrectly think the pressures are equal because they only consider the volume change.
TipFor any expansion ratio r>1, since γ>1, we always have r−γ<r−1. Hence adiabatic final pressure is always less than isothermal final pressure for the same volume increase.
✓Final answerThe correct option is (D).
ANSWER: D
- COMEDK 2025Set 2025-M1 markMCQQ.The ratio of specific heat capacities at constant pressure to that at constant volume for a given mass of a gas is 25. If the percentage increase in volume of the gas while undergoing an adiabatic change is 23, then the percentage decrease in pressure will be: (A) 415 (B) 53 (C) 154 (D) 35
›Reveal solutionSolution
For an adiabatic process, PVγ=constant. Given γ=25 and a 23% increase in volume, the percentage decrease in pressure is found via logarithmic differentiation to be 415%, so the correct option is (A).
The key concept here is the adiabatic relation for an ideal gas: PVγ=constant, where γ=Cp/Cv. When a gas changes adiabatically, pressure and volume are linked so that no heat enters or leaves the system. The problem gives us the percentage change in volume and asks for the corresponding percentage change in pressure — a perfect setup for using logarithmic differentiation to convert small relative changes into each other.
Why this works:
If PVγ=k, taking natural logs gives lnP+γlnV=lnk. Differentiating (for small changes) yields PdP+γVdV=0, so the relative change in pressure is directly proportional to the relative change in volume, with γ as the factor. Percentages are just relative changes multiplied by 100.
Step-by-step solution:
- Write the adiabatic condition For an adiabatic process:
PVγ=constant
Here γ=25.
- Take natural logarithms
lnP+γlnV=constant
- Differentiate (for small changes)
PdP+γVdV=0
This gives the relation between infinitesimal relative changes.
- Solve for the relative change in pressure
PdP=−γVdV
- Plug in the given percentage change in volume The volume increases by 23%, so
VdV=+23×1001=2003
(We keep it as a fraction to avoid decimals.)
- Compute the relative change in pressure
PdP=−25×2003=−40015=−803
- Convert to percentage Percentage change in pressure = PdP×100%=−803×100%=−80300%=−415% The negative sign indicates a decrease.
Thus the percentage decrease in pressure is 415%.
TipNotice that the numbers work out neatly: γ=5/2 and the volume increase is 3/2%, so the pressure decrease is (5/2)×(3/2)=15/4%. Always check if the product simplifies before converting to decimals.
Watch outA common mistake is to forget that the percentage is already given as a pure number (e.g., 3/2 means 1.5%), and then incorrectly multiply by 100 again. Keep everything in fractional form to avoid confusion.
✓Final answerThe correct option is (A).
ANSWER: A
- COMEDK 2023Set 2023-E1 markMCQQ.In an adiabatic expansion of air, the volume is increased by 6.2%. The percentage change in pressure is (γ=1.4) (A) 8.68 (B) 4.84 (C) 6.48 (D) 2.24
›Reveal solutionSolution
So the pressure DECREASES by 8.68 % (the expansion cools and depressurises the gas); the magnitude asked for is 8.68.
Concept: adiabatic process P V^gamma = constant. Taking logs and differentiating gives the fractional-change relation
dP/P = -gamma (dV/V), i.e. % change in P = -gamma x (% change in V).
Given dV/V = +6.2 % and gamma = 1.4:
% change in P = -1.4 x 6.2 = -8.68 %.
So the pressure DECREASES by 8.68 % (the expansion cools and depressurises the gas); the magnitude asked for is 8.68.
✓Final answerThe correct option is (A) — 8.68
ANSWER: A
- COMEDK 2022Set 20221 markMCQQ.There are two identical containers C1 and C2 containing to identical gases. Gas in C1 is reduced to half of its original volume adiabatically, while the gas in container C2 is also reduced to half of its initial volume isothermally. Find the ratio of final pressure in these containers. (γ be the adiabatic constant). (A) 2 : 1 (B) 1 : 2 (C) 2γ:1 (D) 2γ−1:1
›Reveal solutionSolution
Ratio: P1 : P2 = P 2^gamma : 2P = 2^gamma / 2 : 1 = 2^(gamma - 1) : 1
Concept: compare an adiabatic and an isothermal compression of identical gases from the same initial state (P, V) to V/2.
Container C1 (adiabatic): P V^gamma = P1 (V/2)^gamma
P1 = P x 2^gamma
Container C2 (isothermal): P V = P2 (V/2)
P2 = 2P
Ratio:
P1 : P2 = P 2^gamma : 2P = 2^gamma / 2 : 1 = 2^(gamma - 1) : 1
✓Final answerThe correct option is (D) — 2γ−1:1
ANSWER: D
- COMEDK 2021Set 20211 markMCQQ.In an adiabatic process with the ratio of two specific heat, γ=23, pressure is increased by 32%, then decrease in the volume will be (A) 94% (B) 32% (C) 4% (D) 49%
›Reveal solutionSolution
So the volume decreases by 4/9 %.
Concept: for an adiabatic (reversible) process, P V^gamma = constant. Take logarithms and differentiate to relate the fractional changes.
ln P + gamma ln V = constant
=> dP/P + gamma (dV/V) = 0
=> dV/V = -(1/gamma) (dP/P).
Given gamma = 3/2 and dP/P = +2/3 % :
dV/V = -(2/3) * (2/3) % = -(4/9) %.
So the volume decreases by 4/9 %.
✓Final answerThe correct option is (A) — 94%
ANSWER: A
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