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Chemistry · Ch 12 — Chemical Equilibrium

Relationship between Partial Pressure and Concentration

12.4.4

Relationship between Partial Pressure and Concentration

For a mixture of ideal gases, each component's partial pressure is directly proportional to its molar concentration at a fixed temperature. Starting from the ideal gas equation for one component, A, PAV=nARTP_A V=n_A RT, dividing both sides by VV gives PA=nAV×RTP_A=\dfrac{n_A}{V}\times RT. Since nAV\dfrac{n_A}{V} is exactly the molar concentration of A, [A][A], this gives PA=[A]RTP_A=[A]RT. Applying the same reasoning to every other gaseous species in a reaction gives PB=[B]RTP_B=[B]RT, PC=[C]RTP_C=[C]RT, and PD=[D]RTP_D=[D]RT. This simple substitution -- partial pressure equals concentration times RTRT -- is exactly the bridge needed to convert the KpK_p expr …