Chemistry · Ch 2 — Introduction to Analytical Chemistry
Molality
Molality
Molality, denoted m, is defined as the number of moles of solute dissolved per kilogram of solvent (not per kilogram or litre of the whole solution): . Because molality is built entirely from masses — the moles of solute and the mass of solvent — and mass, unlike volume, does not change with temperature, molality itself does not change with temperature, which makes it a more robust concentration unit than molarity for work where the temperature is not tightly controlled. In the laboratory, a solution of some desired, lower concentration is very often prepared by diluting a solution of known, higher concentration with more solvent; that starting, more concentrated solution is called a stoc …
Worked out. Worked example: the density of a 3 M solution of NaCl is 1.25 g mL; calculate its molality. Since molarity is 3 mol L, the mass of NaCl in 1 L of solution g. The mass of 1 L (1000 mL) of solution g (using the given density). Mass of water (solvent) in that litre of solution g kg. Molality $= \dfrac{\text{no. of moles of solute}}{\text{mass of solvent in kg}} = \dfrac{3\text{ mol}}{1.0 …