Skip to content

Chemistry · Ch 2 — Introduction to Analytical Chemistry

Molarity

2.7.3

Molarity

Molarity, denoted M, is the single most widely used way of expressing solution concentration in a laboratory. It is defined as the number of moles of solute dissolved in exactly one litre of the solution: Molarity (M)=no. of moles of solutevolume of solution in litres\text{Molarity } (M) = \dfrac{\text{no. of moles of solute}}{\text{volume of solution in litres}}. Because molarity is defined per unit VOLUME of solution, and the volume that a given mass of solution occupies changes with temperature (liquids expand slightly on heating and contract on cooling), the molarity of a solution is itself dependent on temperature, even though the actual amount of dissolved solute has not changed — only the volume it is dissolved in has. This temperature sensitivity is an important practical limi …

Misc Problem 2.17Calculating the molarity of an NaOH solution

Worked out. Worked example: calculate the molarity of NaOH in a solution prepared by dissolving 4 g of NaOH in enough water to make 250 mL of solution. Molar mass of NaOH =40= 40 g/mol, so moles of NaOH =4/40=0.1= 4/40 = 0.1 mol. Volume of solution =250= 250 mL =0.250= 0.250 L. Molarity M=0.1 mol0.250 L=0.4M = \dfrac{0.1\text{ mol}}{0.250\text{ L}} = 0.4 mol L−1=0.4^{-1} = 0.4 M. …