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Answer the following questions · Q29

Q.With the help of diagram answer the questions given below (the diagram shows the elements Li, Be, O and S):
a. Which atom should have smaller ionization enthalpy, oxygen or sulfur?
b. The lithium forms +1 ions while berylium forms +2 ions?

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Step 1a. Locate O and S. Both are group 16; O is period 2, S is period 3 — S sits directly below O in the same group.

Step 2a. Apply the down-group IE trend. Ionization enthalpy decreases down a group (section 7.5.2.3), so moving from O down to S, IE should decrease.

Step 3a. Answer. Sulfur (S) has the smaller first ionization enthalpy of the two (consistent with the chapter's own Problem 7.6, which places S's first IE near 1000 kJ mol⁻¹, below oxygen's 1314 kJ mol⁻¹ from Table 7.4).

Step 1b. Consider Li's valence configuration. Li is 2s12s^1 — a single valence electron. Removing it leaves the stable, complete-duplet 1s21s^2 [He] core — so Li readily forms Li+Li^+. …

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