Chemistry · Ch 1 — Some Basic Concepts of Chemistry
Physical properties
Physical properties
Mass and weight, though often used loosely as synonyms in everyday speech, are physically distinct: mass is an inherent property of matter, the measure of how much matter a body actually contains, and it does not change with the body's position; weight, on the other hand, is the result of that mass being acted on by gravity, so a body's weight varies depending on how strong the local gravitational pull is (which itself varies with distance from the centre of the earth) — mass is therefore the more fundamental of the two properties. The SI base unit of mass is the kilogram, though the smaller unit 'gram' (1 kg = 1000 g = 10^3 g) is far more convenient for weighing out the small quantities of chemicals typically used in a laboratory. Length comes up in chemistry when discussing very small quantities such as atomic radius, bond length, or the wavelength of electromagnetic radiation, which is why fractional SI length units like the nanometre (1 nm = 10^-9 m) and picometre (1 pm = 10^-12 m) are used instead of the metre itself. Volume is the amount of three-dimensional space a body occupies, independent of its shape; the commonly used unit litre (L) is not itself an SI unit, but is related to the SI unit as 1 L = 1 dm3 = 1000 mL = 1000 cm3, while the true SI unit of volume is the cubic metre (m3). Laboratory glassware such as the graduated cylinder, burette, pipette and volumetric flask are the standard tools used to measure the volume of liquids and solutions with differing degrees of precision. Density is a substance's mass per unit volume, calculated by dividing a measured mass by the corresponding measured volume, and — being independent of how much of the substance is present — it is a characteristic property of that substance; its SI unit works out to kg/m3 (or kg m-3), while the CGS-based unit commonly used in the laboratory is g/mL (equivalently g mL-1 or g cm-3). Temperature is a measure of how hot or cold something is, and three scales are in common use: degree Celsius (°C), degree Fahrenheit (°F), and Kelvin (K) — the last of which is the true SI unit. On …
What this figure shows. A diagram comparing the everyday unit litre with the SI cubic-metre-based volume units. It shows a cube of side 10 cm (equivalently 1 dm) whose volume works out to 1000 cm3, which is shown as equal to 1000 mL, equal to 1 dm3, equal to 1 litre (1 L) — visually anchoring the equivalence '1 L = 1 dm3 = 1000 mL = 1000 cm3' that the running text of this se …
What this figure shows. A labelled illustration of common laboratory glassware used to measure liquid volumes: a 100-mL graduated cylinder marked with mL graduations, a 25-mL pipette carrying a calibration mark for a 25-mL volume, a 50-mL burette that is a long graduated tube fitted with a stopcock/valve at the bottom to control the rate of liquid flow, and a 250-mL volumetric flask carrying a calibration mark for a 250-mL volume. Each piece of glassware is drawn in its characteristic shape (slender bulb pipette, long graduated burette with stopcock, pear-shaped thin-necked volumetric flask) to show how each is suited to a diff …
What this figure shows. A side-by-side diagram of thermometers calibrated on the three common temperature scales discussed in the text — Celsius, Fahrenheit and Kelvin — drawn next to one another so that the same physical reference temperatures can be read off and compared across all three scales at a glance. It marks water's freezing point at sea level as 0°C / 32°F / 273.15K, water's boiling point at sea level as 100°C / 212°F / 373.15K, absolute zero (where all molecular motion stops) as -273.15°C / -459.67°F / 0K, and normal human body temperature as 37°C / 98.6°F, letting a student directly compare how a given physical temperature i …