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Chemistry · Class 11 Science

Ch 1Some Basic Concepts of Chemistry — Class 11 Chemistry, concept-first.

Chemistry is the branch of science devoted to studying matter — everything that occupies space and has mass — along with its physical and chemical properties and the changes matter undergoes under different conditions.

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Key concepts

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Avogadro's Law

At the same temperature and pressure, equal volumes of all gases contain an equal number of molecules (V ∝ n).

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In previous exams

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Chapter contents

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1.1

Introduction

Chemistry is the branch of science devoted to studying matter — everything that occupies space and has mass — along with its physical and chemical properties and the changes matter undergoes under dif…

1.2

Nature of Chemistry

Chemistry is traditionally divided into five branches, each covering a different slice of the subject. Organic chemistry studies the properties and reactions of carbon-containing compounds.

1.2.1

Matter

Matter is anything that occupies space and possesses mass — a fact already familiar from earlier study.

1.2.2

Pure substances versus mixtures

A pure substance has a definite, fixed chemical composition, and as a result it always shows the same set of properties no matter where the sample originally came from — distilled water and a pure met…

1.2.3

States of matter

Matter is already known to exist in three familiar physical states — solid, liquid and gas — a topic taken up in much greater depth later in Unit 3 (Chapter 10).

1.3

Properties of matter and their measurement

Every kind of matter has its own set of characteristic properties, and these fall into two broad categories: physical properties and chemical properties.

1.3.1

Measurement of properties

Many properties of matter — mass, length, area, pressure, volume, time and so on — are quantitative, meaning they can be expressed as a number.

1.3.2

Physical properties

Mass and weight, though often used loosely as synonyms in everyday speech, are physically distinct: mass is an inherent property of matter, the measure of how much matter a body actually contains, and…

1.4

Laws of Chemical Combination

Elements combine with one another to form compounds, and — long before anyone actually knew what a molecular formula was — chemists worked out, purely through careful experimental weighing, a set of b…

1.4.1

Law of conservation of mass

The law of conservation of mass was established by the French scientist Antoine Lavoisier (1743-1794), often called the father of modern chemistry, through a careful series of combustion experiments —…

1.4.2

Law of Definite Proportions

The law of definite proportions (also called the law of definite, or constant, composition) was established by the French chemist Joseph Proust, who compared two samples of cupric carbonate — one that…

1.4.3

Law of multiple proportions

The law of multiple proportions was proposed by John Dalton in 1803, based on the observation that two elements can sometimes combine with each other to form MORE than one distinct compound.

1.4.4

Gay Lussac Law of Gaseous Volume

Gay-Lussac's law of gaseous volumes, put forward by Gay-Lussac in 1808, states that whenever gases combine with each other, or are produced, in a chemical reaction, they always do so in a simple ratio…

1.5

Avogadro Law

Avogadro's law, proposed by Amedeo Avogadro in 1811, states that equal volumes of any gas, measured at the same temperature and pressure, contain an equal number of molecules — regardless of what the…

1.6

Dalton's Atomic Theory

In 1808, John Dalton published a work titled 'A New System of Chemical Philosophy', in which he set out a theory of matter that later came to be known as Dalton's atomic theory.

1.7

Atomic and molecular masses

Having introduced the ideas of atoms and molecules, it is worth pausing to define precisely what is meant by 'atomic mass' and 'molecular mass'.

1.7.1

Atomic Mass

Every element has its own characteristic atomic mass, meaning the mass of a single atom of that element — a genuinely tiny quantity that is not practical to measure directly or to work with in grams (…

1.7.2

Average Atomic Mass

Most elements, as they actually occur in nature, exist not as a single, uniform kind of atom but as a mixture of two or more isotopes — atoms of the same element that carry different individual atomic…

1.7.3

Molecular Mass

The molecular mass of a substance is the mass of a single molecule of that substance, again expressed relative to the mass of one carbon-12 atom (i.e.

1.7.4

Formula Mass

Some substances — sodium chloride is the standard example — do not actually exist as discrete, separate molecules at all.

1.8

Mole concept and molar mass

Because even a very small, weighable amount of any substance contains an enormous number of atoms or molecules, chemists borrow the same idea behind everyday counting words like 'dozen' (12 items) or…

1.9

Moles and gases

Since many chemical substances exist as gases, it is often much more practical to find how many moles of a gas are present by measuring its VOLUME rather than by weighing out its mass.

Answer the following questions

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45 Q
+Show 1 question1 question
  1. Q54Collect information of various scientists and prepare charts of their contribution in chemistry.Preview
+Show 2 questions2 questions
  1. Q3What is an atom and a moleule ? What is the order of magnitude of mass of one atom ? What are isotopes?Free
  2. Q61. One dozen means how many items ? 2. One gross means how many items ?Preview
+Show 3 questions3 questions
  1. Q1Which are mixtures and pure substances from the following ? i. sea water ii. gasoline iii. skin iv. a rusty nail v. a page of the textbook.…Free
  2. Q2Classify the following as element and compound. i. mercuric oxide ii. helium gas iii. water iv. table salt v. iodine vi. mercury vii. oxygen…Preview
  3. Q4If 10 volumes of dihydrogen gas react with 5 volumes of dioxygen gas, how many volumes of water vapour would be produced?Preview
+Show 2 questions2 questions
  1. Q5Find the formula mass of CaSO4. If atomic mass of Ca = 40.1 u, S = 32.1 u and O = 16.0 uFree
  2. Q7Calculate the volume in dm3 occupied by 60.0 g of ethane at STP.Preview
+Show 9 questions9 questions
  1. Q8A sample of pure water, whatever the source always contains ......... by mass of oxygen and 11.1 % by mass of hydrogen. a. 88.9 b. 18 c. 80…Free
  2. Q9Which of the following compounds can NOT demonstrate the law of multiple proportions ? a. NO, NO2 b. CO, CO2 c. H2O, H2O2 d. Na2S, NaFFree
  3. Q10Which of the following temperature will read the same value on Celsius and Fahrenheit scales. a. - 40° b. + 40° c. -80° d. -20°Free
  4. Q11SI unit of the quantity electric current is a. Volt b. Ampere c. Candela d. NewtonPreview
  5. Q12In the reaction N2 + 3H2 ⇌ 2NH3, the ratio by volume of N2, H2 and NH3 is 1 : 3 : 2 This illustrates the law of a. definite proportion b. re…Preview
  6. Q13Which of the following has maximum number of molecules ? a. 7 g N2 b. 2 g H2 c. 8 g O2 d. 20 g NO2Preview
  7. Q14How many g of H2O are present in 0.25 mol of it ? a. 4.5 b. 18 c. 0.25 d. 5.4Preview
  8. Q15The number of molecules in 22.4 cm3 of nitrogen gas at STP is a. 6.022 x 10^20 b. 6.022 x 10^23 c. 22.4 x 10^20 d. 22.4 x 10^23Preview
  9. Q16Which of the following has the largest number of atoms ? a. 1g Au (s) b. 1g Na (s) c. 1g Li (s) d. 1g Cl2 (g)Preview
+Show 4 questions4 questions
  1. Q26homogeneous mixtureFree
  2. Q27heterogeneous mixtureFree
  3. Q28elementPreview
  4. Q29compoundPreview
+Show 18 questions18 questions
  1. Q30What is the ratio of molecules in 1 mole of NH3 and 1 mole of HNO3. (Ans. : 1:1)Free
  2. Q31Calculate number of moles of hydrogen in 0.448 litre of hydrogen gas at STP (Ans. : 0.02 mol)Free
  3. Q32The mass of an atom of hydrogen is 1.008 u. What is the mass of 18 atoms of hydrogen. (18.144 u)Free
  4. Q33Calculate the number of atom in each of the following (Given : Atomic mass of I = 127 u). a. 254 u of iodine (I) b. 254 g of iodine (I) (Ans…Preview
  5. Q34A student used a carbon pencil to write his homework. The mass of this was found to be 5 mg. With the help of this calculate. a. The number…Preview
  6. Q35Arjun purchased 250 g of glucose (C6H12O6) for Rs 40. Find the cost of glucose per mole.Preview
  7. Q36The natural isotopic abundance of 10B is 19.60% and 11B is 80.40 %. The exact isotopic masses are 10.13 and 11.009 respectively. Calculate t…Preview
  8. Q37Convert the following degree Celsius temperature to degree Fahrenheit. a. 40 °C b. 30 °C (Ans. : A. 104 °F, B. 86 °F )Preview
  9. Q38Calculate the number of moles and molecules of acetic acid present in 22 g of it. (Ans. : 0.3666 mol, 2.2076 x 10^23 molecules )Preview
  10. Q3924 g of carbon reacts with some oxygen to make 88 grams of carbon dioxide. Find out how much oxygen must have been used. (Ans. : 64.0 )Preview
  11. Q40Calculate number of atoms is each of the following. (Average atomic mass : N = 14 u, S = 32 u) a. 0.4 mole of nitrogen b. 1.6 g of sulfur (A…Preview
  12. Q412.0 g of a metal burnt in oxygen gave 3.2 g of its oxide. 1.42 g of the same metal heated in steam gave 2.27 of its oxide. Which law is veri…Preview
  13. Q42In two moles of acetaldehyde (CH3CHO) calculate the following a. Number of moles of carbon b. Number of moles of hydrogen c. Number of moles…Preview
  14. Q43Calculate the number of moles of magnesium oxide, MgO in i. 80 g and ii. 10 g of the compound. (Average atomic masses of Mg = 24 and O = 16)…Preview
  15. Q44What is volume of carbon dioxide, CO2 occupying by i. 5 moles and ii. 0.5 mole of CO2 gas measured at STP. (Ans. i. 112 dm3 ii. 11.2dm3)Preview
  16. Q45Calculate the mass of potassium chlorate required to liberate 6.72 dm3 of oxygen at STP. Molar mass of KClO3 is 122.5 g mol-1. (Ans. 24.5 g)Preview
  17. Q46Calculate the number of atoms of hydrogen present in 5.6 g of urea, (NH2)2CO. Also calculate the number of atoms of N, C and O. (Ans. : No.…Preview
  18. Q47Calculate the mass of sulfur dioxide produced by burning 16 g of sulfur in excess of oxygen in contact process. (Average atomic mass : S = 3…Preview
+Show 6 questions6 questions
  1. Q48The need of the term average atomic mass.Free
  2. Q49Molar mass.Free
  3. Q50Mole concept.Preview
  4. Q51Formula mass with an example.Preview
  5. Q52Molar volume of gas.Preview
  6. Q53Types of matter (on the basis of chemical composition).Preview