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Exercises · 7.3

Q.Discuss the trends in chemical reactivity of group 15 elements.

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Step 1: Metallic/nonmetallic character.

Going down the group, metallic character increases: N and P are nonmetals, As and Sb are metalloids, and Bi is essentially a metal. This is reflected in the nature of their oxides — acidic (N, P) → amphoteric (As, Sb) → basic (Bi).

Step 2: Oxidation-state stability.

The relative stability of the +5+5 oxidation state decreases while that of +3+3 increases down the group (inert pair effect), so Bi2O5Bi_2O_5/BiCl5BiCl_5 are strong oxidising agents whereas N2O5N_2O_5/PCl5PCl_5 are comparatively stable, common compounds.

Step 3: Hydrides (EH3EH_3).

Thermal stability of hydrides decreases down the group (NH3>PH3>AsH3>SbH3>BiH3NH_3 > PH_3 > AsH_3 > SbH_3 > BiH_3) as the E–H bond weakens with increasing atomic size; correspondingly, their reducing character increases down the group, and their basic strength (ability to donate the lone pair) decreases down the group.

Step 4: Reactivity with oxygen/halogens.

All members combine with oxygen and halogens, but the ease and the type of oxide/halide formed varies systematically with the increasing metallic character and decreasing tendency to form multiple bonds down the group.

✓Final answer

Down Group 15, elements become progressively more metallic, their oxides become less acidic, hydride stability/basicity decreases while hydride reducing power increases, and the higher (+5+5) oxidation state becomes progressively less stable relative to +3+3.

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