Q.Discuss the trends in chemical reactivity of group 15 elements.
Step 1: Metallic/nonmetallic character.
Going down the group, metallic character increases: N and P are nonmetals, As and Sb are metalloids, and Bi is essentially a metal. This is reflected in the nature of their oxides — acidic (N, P) → amphoteric (As, Sb) → basic (Bi).
Step 2: Oxidation-state stability.
The relative stability of the oxidation state decreases while that of increases down the group (inert pair effect), so / are strong oxidising agents whereas / are comparatively stable, common compounds.
Step 3: Hydrides ().
Thermal stability of hydrides decreases down the group () as the E–H bond weakens with increasing atomic size; correspondingly, their reducing character increases down the group, and their basic strength (ability to donate the lone pair) decreases down the group.
Step 4: Reactivity with oxygen/halogens.
All members combine with oxygen and halogens, but the ease and the type of oxide/halide formed varies systematically with the increasing metallic character and decreasing tendency to form multiple bonds down the group.
Down Group 15, elements become progressively more metallic, their oxides become less acidic, hydride stability/basicity decreases while hydride reducing power increases, and the higher () oxidation state becomes progressively less stable relative to .
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