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NCERT Exemplar · Q14

Q.Consider a metal exposed to light of wavelength 600 nm600\ \text{nm}. The maximum energy of the electron doubles when light of wavelength 400 nm400\ \text{nm} is used. Find the work function in eV.

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The problem uses the photoelectric equation Kmax=hf−ϕK_{\text{max}} = hf - \phi for two wavelengths. The ratio of maximum kinetic energies is given (doubles), which lets us eliminate the unknown KmaxK_{\text{max}} and solve directly for the work function ϕ\phi. The answer is ϕ≈1.03 eV\phi \approx 1.03\ \text{eV}.

The photoelectric effect tells us that when light hits a metal, an electron can be ejected if the photon energy exceeds the work function. The leftover energy becomes the electron’s maximum kinetic energy. Here, we have two different wavelengths, and we know that the maximum kinetic energy for the second case is exactly twice that of the first. That’s the only link between the two situations — and it’s enough to find the work function.

Let’s set it up.

  1. Write the photoelectric equation for each case. For wavelength λ1=600 nm\lambda_1 = 600\ \text{nm}, let the maximum kinetic energy be K1K_1. For λ2=400 nm\lambda_2 = 400\ \text{nm}, it’s K2K_2, and we’re told K2=2K1K_2 = 2K_1. The photon energy is hc/λhc/\lambda, so:

K1=hcλ1−ϕK_1 = \frac{hc}{\lambda_1} - \phi

K2=hcλ2−ϕK_2 = \frac{hc}{\lambda_2} - \phi

  1. Use the doubling condition. Since K2=2K1K_2 = 2K_1, substitute:

hcλ2−ϕ=2(hcλ1−ϕ)\frac{hc}{\lambda_2} - \phi = 2\left(\frac{hc}{\lambda_1} - \phi\right)

  1. Solve for ϕ\phi. Expand the right side:

hcλ2−ϕ=2hcλ1−2ϕ\frac{hc}{\lambda_2} - \phi = \frac{2hc}{\lambda_1} - 2\phi

Bring the ϕ\phi terms together:

−ϕ+2ϕ=2hcλ1−hcλ2-\phi + 2\phi = \frac{2hc}{\lambda_1} - \frac{hc}{\lambda_2}

ϕ=hc(2λ1−1λ2)\phi = hc\left(\frac{2}{\lambda_1} - \frac{1}{\lambda_2}\right)

This is the clean algebraic result. Notice that the unknown K1K_1 cancelled out completely — that’s the power of using the ratio.

  1. Plug in the numbers. Use hc=1240 eV⋅nmhc = 1240\ \text{eV·nm} (a standard and very convenient value for problems in eV and nm). …

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