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Q.A real gas obeys Boyle's law at

(a) high temperature and high pressure
(b) high temperature and low pressure
(c) low temperature and low pressure
(d) low temperature and high pressure
Manipur CohsemCouncil of Higher Secondary Education, Manipur (Higher Secondary 1st Year) 2021MCQ· 1mImportance★★★★★
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A real gas approximates ideal-gas (Boyle's law) behaviour when its molecules are far apart and moving fast — i.e. at high temperature and low pressure — option (b).

Boyle's law (PV=constantPV = \text{constant} at constant temperature) is strictly valid only for an ideal gas, whose molecules are assumed to have negligible volume and no intermolecular forces of attraction.

Real gases deviate from this ideal behaviour because their molecules do occupy a finite volume and do exert weak attractive forces on each other (accounted for in the van der Waals equation via the correction terms aa and bb). These deviations become significant when the gas is compressed to high pressure (molecules packed close, own volume matters, attractions matter) or cooled to low temperature (molecules move slowly, attractive forces have more effect, gas may even liquefy).

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