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Q.What is the basic structural difference between starch and cellulose?

Meghalaya MboseMBOSE Meghalaya Intermediate Board 2025Subjective· 1mImportance★★★★★
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Both are glucose polymers, but they differ in the type of glycosidic linkage joining the glucose units — α\alpha in starch, β\beta in cellulose — which changes the overall shape and digestibility of the polymer.

Structural comparison

  • Starch is a polymer of α\alpha-D-glucose units. It consists of two components: amylose (a long unbranched chain of glucose units joined by α(1→4)\alpha(1\rightarrow4)-glycosidic linkages, which coils into a helical structure) and amylopectin (a branched-chain polysaccharide of glucose units joined mainly by α(1→4)\alpha(1\rightarrow4) linkages, with branching through α(1→6)\alpha(1\rightarrow6)-glycosidic linkages roughly every 25 units).
  • Cellulose is a polymer made up only of β\beta-D-glucose units, joined exclusively by β(1→4)\beta(1\rightarrow4)-glycosidic linkages, forming a long, straight, unbranched chain. These linear chains run parallel and are extensively hydrogen-bonded to each other, giving cellulose fibres great mechanical strength (as in the plant cell wall). …

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