Q.What is molarity of 10% NaOH (W/V) solution?
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🔒 Start your 14-day free trial to unlock the full solution →Concept understanding — Mass Percentage
Mass Percentage: The Intuition
Imagine you're making lemonade. You mix 50 grams of sugar into 200 grams of water. The total drink weighs 250 grams. Now, if someone asks, "How much of this drink is actually sugar?" — you're not just saying "50 grams." You want to say what fraction of the whole mixture is sugar, scaled to a convenient 100.
That's mass percentage. It answers: "Out of every 100 grams of the mixture, how many grams are this particular component?"
In our lemonade, sugar is 50 g out of 250 g total. That's 25050=0.2 of the whole. Multiply by 100 to get the percentage: 0.2×100=20%. So, 20% of the drink's mass is sugar. If you had 100 g of this lemonade, 20 g of it would be sugar.
The Precise Definition
Mass percentage of component=Total mass of mixtureMass of that component×100%
The formula is simple, but the key is understanding what "total mass" means. It's the sum of masses of all components in the mixture — nothing more, nothing less.
Why It Matters in Chemistry
Mass percentage is one of the most common ways to express concentration — how much of a substance is present in a mixture. You'll see it in:
- Solutions: "10% salt water" means 10 g of salt dissolved in enough water to make 100 g of solution (not 10 g salt + 100 g water — that would be 110 g total, giving only about 9.1%).
- Alloys: "18-karat gold" is 75% gold by mass (18 parts gold out of 24 total parts).
- Food labels: "Fat: 15%" means 15 g of fat per 100 g of the food.
A Common Mistake
Students often think "10% salt solution" means 10 g salt + 100 g water. That's wrong. It means 10 g salt + 90 g water = 100 g total solution. The denominator is total mass, not the mass of the solvent alone.
Step-by-Step Example
Problem: A solution is made by dissolving 25 g of glucose in 175 g of water. Find the mass percentage of glucose.
Step 1: Identify the component you care about — glucose (25 g).
Step 2: Find the total mass of the mixture.
Total mass=25 g (glucose)+175 g (water)=200 g
Step 3: Apply the formula.
Mass percentage of glucose=20025×100%=12.5% …
Why this formula?
Let's break down Mass Percentage from first principles. The goal is to understand why the formula is what it is, not just to memorize it.
1. The Core Idea: "Part of a Whole"
Mass percentage answers a simple question: "If I break a mixture into 100 equal parts by mass, how many of those parts come from a specific component?"
Imagine you have a bowl of fruit salad. The total mass is 500 grams. The apples in it weigh 100 grams.
- The apples are a part of the whole salad.
- The whole salad is the total.
The mass percentage tells you the fraction of the total mass that is apples, but expressed "out of 100" (per cent).
2. The Natural First Step: The Fraction
Before we talk about "percentage," we talk about the fraction of the total:
Fraction of component=Total mass of mixtureMass of component
For the apple example:
500 g100 g=0.2
This means 0.2 (or one-fifth) of the total mass is apples. This is the pure ratio — no scaling yet.
3. Why Multiply by 100?
A fraction like 0.2 is perfectly correct, but it's not intuitive for quick comparison. "Per cent" literally means "per hundred" (from Latin per centum).
To convert a fraction into a "per hundred" number, we multiply by 100:
Percentage=(Fraction)×100
So:
0.2×100=20%
This tells us: "Out of every 100 grams of fruit salad, 20 grams come from apples." That's much easier to visualize.
4. The Final Formula (The "Why" in One Line)
Putting the fraction and the "times 100" together gives the standard formula:
Mass percentage=Total mass of mixtureMass of component×100%
Why does this work?
Because it's just:
- Find the proportion (part ÷ whole).
- Scale that proportion to per hundred (× 100).
5. A Common Exam Trap (and Why It's Wrong)
Sometimes students write: …
A 10% (W/V) NaOH solution contains 10 g NaOH in 100 mL, i.e. 100 g per litre. Dividing by the molar mass (40 g/mol) gives the …
10% (W/V) NaOH = 2.5 mol/L.
10% (W/V) means 10 g of NaOH dissolved to make 100 mL of solution.
Step 1 - mass of NaOH per litre: 10 g in 100 mL = 100 g in 1000 mL (1 L). …
- CBSE 2025Set ANNUAL1 markQ.What is parts per million (ppm) concentration of a solution?
›Reveal solutionSolution
ppm expresses solute content as parts per million parts of solution, used for very dilute solutions.
Parts per million (ppm) is a way of expressing the concentration of a very dilute solution, defined as the number of parts of solute present per million (106) parts of the solution (which may be expressed on a mass, volume, or mass/volume basis):
…
- CBSE 2018Set ANNUAL1 markQ.What is molarity of 10% NaOH (W/V) solution?
›Reveal solutionSolution
10% (W/V) NaOH = 2.5 mol/L.
10% (W/V) means 10 g of NaOH dissolved to make 100 mL of solution.
Step 1 - mass of NaOH per litre: 10 g in 100 mL = 100 g in 1000 mL (1 L). …
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