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NCERT Exemplar · Q1

Q.An ideal gas undergoes four different processes starting from the same initial state, drawn on a PP-VV diagram (pressure PP vertical, volume VV horizontal). The four processes are, in some order, adiabatic, isothermal, isobaric and isochoric. Starting from the common initial point (upper-left region): curve 4 is the flat, topmost curve along which the pressure barely changes as the volume increases; curve 3 falls off below it as the volume increases; curve 2 is the lowest of the three expansion curves, falling most steeply as the volume increases; and curve 1 is a vertical line dropping straight down from the initial state (volume unchanged, pressure decreasing). Which numbered curve is the adiabatic process?

(a) 4
(b) 3
(c) 2
(d) 1
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✓ Free question

The slope of a process on a PP-VV diagram tells you what it is: horizontal (slope 0) is isobaric, vertical is isochoric, and between them the adiabatic is steeper than the isothermal. Curve 4 is isobaric, curve 1 isochoric, curve 3 isothermal and curve 2 — the steepest of the expansion curves — is adiabatic.

Concept

For each process the slope dPdV\dfrac{dP}{dV} at the common starting state is:

  • Isobaric (P=P=const): dPdV=0\dfrac{dP}{dV}=0 → horizontal line.
  • Isothermal (PV=PV=const): dPdV=−PV\dfrac{dP}{dV}=-\dfrac{P}{V}.
  • Adiabatic (PVγ=PV^{\gamma}=const): dPdV=−γPV\dfrac{dP}{dV}=-\gamma\dfrac{P}{V}, which is γ\gamma times steeper than the isothermal (since γ>1\gamma>1).
  • Isochoric (V=V=const): vertical line, slope −∞-\infty.

Ranking the curves

Starting from the same point, order of steepness (least to most negative) is: isobaric (flat) << isothermal << adiabatic << isochoric (vertical). Matching to the diagram:

  • Curve 4 (flat, top) == isobaric.
  • Curve 3 (moderate fall) == isothermal.
  • Curve 2 (steepest fall) == adiabatic.
  • Curve 1 (vertical) == isochoric.

Distractors: (A) 4 is isobaric, (D) 1 is isochoric, (B) 3 is isothermal — all wrong because the adiabatic must lie between the isothermal and the vertical isochoric.

✓Final answer

Option (C) — curve 2 is the adiabatic process.

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