Write Brief Answer · Q23
Q.Briefly give the basis for pauling's scale of electronegativity.
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Start your 14-day free trial to unlock the full solution →Step 1. Electronegativity cannot be measured directly, so Pauling built a numerical scale instead. He started by arbitrarily assigning hydrogen an electronegativity of 2.1 and fluorine 4.0.
Step 2. For any other bonded pair A-B, he calculated the DIFFERENCE in their electronegativities from the 'extra' bond dissociation energy of the real A-B bond compared to what a purely non-polar (average of A-A and B-B) bond would have:
where are the bond dissociation energies (kcal) of AB, A2 and B2 respectively. …
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