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Question 56 of 66

Q.How will you convert acetone into propane ?

Puducherry TnboardTamil Nadu HSC (DGE) Board 2023Subjective· 2mImportance★★★★★
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Clemmensen reduction — treating the ketone with zinc amalgam and concentrated hydrochloric acid — reduces acetone's carbonyl group directly to −CH2−-CH_2-, converting it to propane.

Acetone, CH3−CO−CH3CH_3-CO-CH_3, is a ketone whose carbonyl carbon can be fully reduced to a methylene (-CH2_2-) carbon using Clemmensen reduction: the ketone is refluxed with zinc amalgam [Zn(Hg)] in the presence of concentrated hydrochloric acid. CH3−CO−CH3→conc. HClZn(Hg)CH3−CH2−CH3CH_3-CO-CH_3 \xrightarrow[\text{conc. }HCl]{Zn(Hg)} CH_3-CH_2-CH_3 This reaction proceeds under strongly acidic conditions and is used specifically when the rest of the molecule is stable to acid (an alternative, base-mediated method — Wolff-Kishner redu …

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