Q.Write a short note on anamolous properties of the first element of p-block.
Step 1. Three factors together explain why the first member of every p-block group differs from the rest of its family: its exceptionally small size, its high ionisation enthalpy and high electronegativity, and the complete absence of d orbitals in its valence shell.
Step 2. Boron (group 13). Boron is a metalloid while the rest of group 13 are reactive metals; it shows a diagonal relationship with silicon (group 14) -- both elements' oxides are acidic, both form readily hydrolysed covalent hydrides, and (except for boron trifluoride) both elements' halides hydrolyse readily.
Step 3. Carbon (group 14). Carbon is strictly a non-metal, unlike the metalloid/metal members below it; uniquely it forms multiple bonds (C=C, C=O) and shows an exceptional tendency to catenation, which then collapses sharply down the group (C >> Si > Ge ≈ Sn > Pb).
Step 4. Nitrogen (group 15) and oxygen (group 16). Nitrogen, like carbon, forms multiple bonds (N=N, C=N, N=O) and, unusually for its group, exists as a diatomic gas; oxygen likewise exists as a diatomic gas unlike the rest of its family, and its high electronegativity lets it hydrogen-bond.
Step 5. Fluorine (group 17). The most electronegative element overall, fluorine also hydrogen-bonds; it shows only the -1 oxidation state (the heavier halogens can reach +1, +3, +5, +7 too); and it is both the strongest oxidising agent and the most reactive halogen.
The first member of every p-block group is anomalous because of its small size, high ionisation enthalpy/electronegativity and absence of d orbitals -- seen concretely in boron's metalloid/diagonal-relationship behaviour, carbon's multiple bonding and catenation, nitrogen's and oxygen's diatomic gaseous existence, and fluorine's unique -1-only, most-reactive halogen behaviour.
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