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Question 48 of 58

Q.An element belongs to group-15 and 3rd3^{rd} period of the periodic table. Its electronic configuration would be :

(a) 1s2 2s2 2p6 3s2 3p21s^2\,2s^2\,2p^6\,3s^2\,3p^2
(b) 1s2 2s2 2p41s^2\,2s^2\,2p^4
(c) 1s2 2s2 2p6 3s2 3p31s^2\,2s^2\,2p^6\,3s^2\,3p^3
(d) 1s2 2s2 2p31s^2\,2s^2\,2p^3
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The group-15, period-3 element is phosphorus, Z=15, with configuration 1s2 2s2 2p6 3s2 3p31s^2\,2s^2\,2p^6\,3s^2\,3p^3.

Group 15 elements have 5 valence electrons (ns2np3ns^2np^3), and period 3 means the outermost shell is n=3. Filling the orbitals in order: 1s21s^2 (n=1, 2 electrons), 2s2 2p62s^2\,2p^6 (n=2, 8 electrons), 3s2 3p33s^2\,3p^3 (n=3, 5 electrons) — a total of 15 electrons, matching atomic number 15 (phosphorus). Option (a) has only 2 electrons in 3p, which is silicon (Z=14, group 14). Option (b), 1s2 2s2 2p41s^2\,2s^2\,2p^4, is oxygen (Z=8, group 16, period 2 …

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