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NCERT Exemplar · Q59

Q.When kept in water, raisin swells in size. Name and explain the phenomenon involved with the help of a diagram. Give three applications of the phenomenon.

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The swelling of a raisin in water is due to endosmosis — water moves into the raisin cells across a semipermeable membrane because the cell sap has a higher solute concentration than the surrounding water. The final answer is endosmosis.

Concept and Intuition

Why does a dry raisin plump up when soaked in water? The key lies in osmosis — the net movement of solvent (water) from a region of lower solute concentration to a region of higher solute concentration through a semipermeable membrane.

A raisin is essentially a dehydrated grape. Its cells contain concentrated sugars, salts, and other solutes (the cell sap). The cell membrane acts as a semipermeable barrier: it lets water molecules pass through freely but blocks the larger solute molecules. When you place the raisin in pure water (which has almost zero solutes), the water outside is much more dilute than the sap inside. Nature tries to equalise concentrations, so water rushes into the cells. This inward movement of water is called endosmosis (from Greek endon = within + ōsmos = push). The cells swell, and the raisin as a whole becomes turgid and increases in size.

Osmotic pressure (Π\Pi) is given by van't Hoff's law:

Π=iCRT\Pi = iCRT

where ii is the van't Hoff factor, CC is molar concentration, RR is the gas constant, and TT is absolute temperature. The higher the solute concentration inside the cell, the greater the osmotic pressure, and the stronger the "pull" for water to enter.

Step-by-Step Explanation

  1. Identify the two solutions separated by the membrane.

    • Inside the raisin cells: A concentrated solution of sugars, organic acids, and minerals (cell sap).
    • Outside the raisin: Pure water (or very dilute water).
    • The membrane: The cell membrane (plasma membrane) of each raisin cell, which is selectively permeable.
  2. Compare their water potentials.

    Water potential (Ψ\Psi) is a measure of the tendency of water to move. Pure water has the highest water potential (taken as 0 at standard conditions). A solution has a lower (more negative) water potential because solutes "tie up" water molecules.

    • Ψoutside≈0\Psi_{\text{outside}} \approx 0 (pure water)
    • Ψinside<0\Psi_{\text{inside}} < 0 (concentrated sap) Water always moves from a region of higher water potential to lower water potential — i.e., from outside to inside.
  3. Describe the net movement of water.

    Water molecules diffuse through the semipermeable membrane into the cells. This is endosmosis. The cells swell as they take up water, exerting pressure against the cell wall (turgor pressure). The raisin becomes plump and firm.

  4. Contrast with exosmosis.

    If you placed the raisin in a concentrated sugar solution (higher solute concentration outside), water would leave the cells — the raisin would shrink further. That outward movement is exosmosis.

Watch out

A common mistake is to say the raisin swells because it "absorbs water" without specifying the mechanism. Absorption alone is not enough — the key is that water moves across a semipermeable membrane due to a concentration gradient. That is what distinguishes osmosis from simple diffusion or capillary action.

Diagram

Below is a simple schematic of the process. (Imagine the raisin cell as a box with a dotted membrane.) …

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