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Exercises · 12.9

Q.The radius of the innermost electron orbit of a hydrogen atom is 5.3×10−11 m5.3 \times 10^{-11}\ \text{m}. What are the radii of the n=2n = 2 and n=3n = 3 orbits?

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In the Bohr model, the radius of an electron orbit scales as n2n^2 times the Bohr radius r1r_1. Given r1=5.3×10−11 mr_1 = 5.3 \times 10^{-11}\ \text{m}, the radii for n=2n=2 and n=3n=3 are 2.12×10−10 m2.12 \times 10^{-10}\ \text{m} and 4.77×10−10 m4.77 \times 10^{-10}\ \text{m}, respectively.

The Bohr model of the hydrogen atom is built on a simple but powerful idea: the electron can only occupy certain allowed orbits where its angular momentum is an integer multiple of h2π\frac{h}{2\pi}. This quantization condition leads directly to a neat scaling law for orbit radii.

For a hydrogen-like atom (one electron orbiting a nucleus of charge +Ze+Ze), the centripetal force comes from the Coulomb attraction:

mv2r=14πε0Ze2r2\frac{mv^2}{r} = \frac{1}{4\pi\varepsilon_0} \frac{Ze^2}{r^2}

Combine this with Bohr’s quantization of angular momentum:

mvr=nh2πmvr = n\frac{h}{2\pi}

Solving these two equations eliminates vv and gives the radius of the nnth orbit:

rn=4πε0h24π2me2⋅n2Z=a0n2Zr_n = \frac{4\pi\varepsilon_0 h^2}{4\pi^2 m e^2} \cdot \frac{n^2}{Z} = a_0 \frac{n^2}{Z}

where a0=5.3×10−11 ma_0 = 5.3 \times 10^{-11}\ \text{m} is the Bohr radius — the radius of the innermost orbit (n=1n=1) for hydrogen (Z=1Z=1).

rn=n2⋅r1r_n = n^2 \cdot r_1

This is the key: the radius grows as the square of the principal quantum number nn. No need to re-derive constants each time — once you know r1r_1, all higher orbits follow immediately.

Now let’s apply it step by step.

  1. Identify the given data.

    The innermost orbit radius r1=5.3×10−11 mr_1 = 5.3 \times 10^{-11}\ \text{m}. This is the Bohr radius for hydrogen.

  2. Write the general relation.

    For hydrogen (Z=1Z=1):

rn=n2⋅r1r_n = n^2 \cdot r_1

  1. Find r2r_2 (for n=2n=2). …

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