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NCERT Exemplar · Q12

Q.Which of the following statement(s) is/are not true about the following decomposition reaction.
2KClO3 → 2KCl + 3O2 (Note: more than one of the given options may be correct.)

(i) Potassium is undergoing oxidation
(ii) Chlorine is undergoing oxidation
(iii) Oxygen is reduced
(iv) None of the species are undergoing oxidation or reduction
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In the decomposition of 2 KClOX3→2 KCl+3 OX2\ce{2KClO3 -> 2KCl + 3O2}, chlorine is reduced (from +5 to −1), oxygen is oxidised (from −2 to 0) and potassium stays at +1. Statement by statement, all four given statements are not true.

To identify what is actually happening in this reaction, we need to track the oxidation states of each element before and after the decomposition. A redox reaction involves the transfer of electrons: oxidation means losing electrons (oxidation state increases), while reduction means gaining electrons (oxidation state decreases).

The key insight here is that not every element in a compound necessarily undergoes a change. Some atoms are simply spectators, maintaining their oxidation state while the compound rearranges around them.

Determining oxidation states

Let me assign oxidation numbers to each element in both reactant and products.

In KClOX3\ce{KClO3} (potassium chlorate):

  • Potassium (K) is a Group 1 metal: +1+1
  • Oxygen typically has oxidation state: −2-2
  • For chlorine (Cl), using the fact that the compound is neutral:

+1+x+3(−2)=0+1 + x + 3(-2) = 0

x=+5x = +5

In KCl\ce{KCl} (potassium chloride):

  • Potassium: +1+1
  • Chlorine: −1-1

In OX2\ce{O2} (elemental oxygen):

  • Oxygen in its elemental form: 00

Tracking the changes

Now I'll compare the oxidation states before and after:

ElementIn reactantIn productChangeProcess
K+1+10No change
Cl+5−1−6Reduction
O−20+2Oxidation
  1. Potassium stays at +1+1 throughout. It is neither oxidised nor reduced; it's a spectator ion that simply tags along while the real chemistry happens elsewhere.

  2. Chlorine drops from +5+5 to −1-1, a decrease of 6 units. This means chlorine gains electrons and is reduced. Each chlorine atom accepts 6 electrons.

  3. Oxygen rises from −2-2 to 00, an increase of 2 units. This means oxygen loses electrons and is oxidised. Each oxygen atom donates 2 electrons.

Tip

In decomposition reactions of oxyanions like chlorate, the central atom (here Cl) is often in a high positive oxidation state and gets reduced, while the oxygen gets oxidised to its elemental form.

Evaluating each statement

(i) Potassium is undergoing oxidation — NOT TRUE. Potassium remains at +1; no electron transfer occurs for this element. …

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