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Chemistry · Ch 1 — Basic Concepts of Chemistry and Chemical Calculations

Molar Volume

1.4.3

Molar Volume

Molar volume is the volume occupied by one mole of any substance in the gaseous state, at a stated temperature and pressure. Because one mole of any gas contains the same number of molecules (Avogadro's hypothesis), one mole of any ideal gas occupies the same volume under the same conditions -- regardless of which gas it is. The commonly used reference values are:

ConditionsMolar volume
273 K and 1 bar pressure (STP)22.71 L
273 K and 1 atm pressure22.4 L
298 K and 1 atm pressure (Room Temperature and Pressure, SATP)24.47 L
Table ~table-molar-volumeVolume occupied by one mole of a gaseous substance
ConditionsVolume occupied by one mole of any gaseous substance (litre)
273 K and 1 bar pressure (STP)22.71
273 K and 1 atm pressure22.4
Misc Evaluate Yourself 3Moles of ethane; molecules of oxygen gas

Worked out. An in-text practice box with two parts: (3a) calculate the number of moles present in 9 g of ethane; (3b) calculate the number of molecules of oxygen gas that occupies a volume of 224 ml at 273 K and 3 atm pressure. …