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Chemistry · Ch 10 — Chemical Bonding

Bond Order

10.5.2

Bond Order

Bond order is the number of bonds formed between two bonded atoms in a molecule. In simple Lewis theory, bond order equals the number of shared electron pairs between the two bonded atoms.

  • A single shared pair gives bond order 1 (e.g. H-H in H₂; likewise the central atom's bonds in H₂O, HCl, or methane are all single bonds of order 1).
  • Two shared pairs give bond order 2 (e.g. O=O in O₂; C=O in formaldehyde, HCHO; C=C in ethylene, C₂H₄).
  • Three shared pairs give bond order 3 (e.g. N≡N in N₂; C≡N in HCN). …
Table 10.2Bond order of some common bonds
S.NoMoleculeBonded atomsBond order
1H₂H-H1
2O₂O=O2
3N₂N≡N3
4HCNC≡N3
5HCHOC=O2