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Question 56 of 84

Q.Statement (I): Electrovalent compounds possess high lattice enthalpy, high melting and boiling points.
Statement (II): Due to strong coulombic forces of attraction between the oppositely charged ions, electrovalent compounds exist mostly as hard crystalline solids.

(a) Statement (I) is correct but statement (II) is false.
(b) Statements (I) and (II) are correct and statement (II) is the correct explanation of statement (I).
(c) Statement (I) is false but statement (II) is correct.
(d) Statements (I) and (II) are correct and statement (I) is not correct explanation of statement (II).
Tamil Nadu DgeTamil Nadu HSC First Year (DGE) Board 2018MCQ· 1mImportance★★★★★
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Both statements are true, and the strong coulombic attraction described in Statement II is exactly what causes the high lattice enthalpy and high melting/boiling points described in Statement I.

Electrovalent (ionic) compounds are held together by strong electrostatic (coulombic) forces between oppositely charged ions arranged in a regular three-dimensional lattice. Breaking this lattice apart (melting or vaporizing it) requires overcoming these strong forces, which is why ionic compounds have high lattice enthalpy and correspondingly high melting and boiling points - this is exactly Statement I. Statement II explains WHY: because the coulombic forces between the ions are strong, the ions pack tightly into a rigid, ordered crystal lattice, making th …

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