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Chemistry · Ch 4 — Hydrogen

Chemical properties of Deuterium

4.3.3

Chemical properties of Deuterium

Deuterium's chemistry closely parallels ordinary hydrogen's. Like H₂, it reacts with oxygen to form the deuterium analogue of water -- deuterium oxide, better known as heavy water:

2 D2+O2→2 D2O2\,D_2 + O_2 \rightarrow 2\,D_2O

It also reacts with the halogens to give the corresponding deuterium halides:

D2+X2→2 DX(X=F, Cl, Br, I)D_2 + X_2 \rightarrow 2\,DX \qquad (X = F,\ Cl,\ Br,\ I)

Deuterium exchange reactions. Beyond simply reacting the way H₂ does, deuterium has a distinctive reaction type of its own: it can reversibly replace ordinary hydrogen already present in a compound, either partially or completely depending on the reaction conditions, whenever the compound is treated with D₂ gas or heavy water. Examples:

CH4+2 D2→CD4+2 H2CH_4 + 2\,D_2 \rightarrow CD_4 + 2\,H_2

2 NH3+3 D2→2 ND3+3 H22\,NH_3 + 3\,D_2 \rightarrow 2\,ND_3 + 3\,H_2 …