Chemistry · Ch 4 — Hydrogen
Isotopes of Hydrogen
Isotopes of Hydrogen
Hydrogen has three naturally-occurring isotopes -- atoms with the same one proton (and hence the same atomic number, 1) but different numbers of neutrons:
- Protium (, usually just written H) -- the ordinary form, with no neutron at all. It is overwhelmingly the most common isotope, making up 99.985% of natural hydrogen, and it is the only one of the three that contains no neutron.
- Deuterium (, symbol D), also called heavy hydrogen, has one proton and one neutron, and constitutes about 0.015% of natural hydrogen.
- Tritium (, symbol T) has one proton and two neutrons. It is radioactive and occurs only in extremely small traces -- roughly one atom per 10¹⁸ hydrogen atoms.
Since natural hydrogen is a mixture of all three isotopes, and hydrogen exists as the diatomic molecule, combining two atoms at random from this mixture gives rise to six possible molecular species: H₂, HD, D₂, HT, T₂ and DT. …
What this figure shows. Three ball-and-stick/space-filling atomic models, one for each isotope, each drawn as a pale green electron-cloud sphere with a small orbiting electron dot and a central coloured nucleus. Protium's nucleus is a single pink/purple sphere (1 proton, 0 neutrons). Deuterium's nucleus pairs one pink proton with one white/grey neutron (1 proton, 1 neutron). Tritium's nucleus shows one pink proton together with two white/grey neutrons (1 proton, 2 neutrons) -- visually sh …
| Property | Protium | Deuterium | Tritium |
|---|---|---|---|
| Atomic Hydrogen | |||
| Symbol | H | D | T |
| Atomic mass (amu) | 1.008 | 2.014 | 3.016 |
| No. of electrons / protons / neutrons | 1 / 1 / 0 | 1 / 1 / 1 | 1 / 1 / 2 |
| Nuclear stability | Stable | Stable | Radioactive (t½ = 12.3 yrs) |
| Molecular Hydrogen | |||
| Molecule | H₂ | D₂ | T₂ |
| Abundance (%) | 99.985 | 0.0156 | ~10⁻¹⁵ |
| Molecular mass (amu) | 2.016 | 4.028 | 6.032 |
| Melting point (K) | 13.96 | 18.73 | 20.62 |
| Boiling point (K) | 20.39 | 23.67 | 25.04 |
| Internuclear distance (pm) | 74.14 | 74.14 | 74.14 |
| Critical Temperature (K) | 33.19 | 38.35 | 40.60 |