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Chemistry · Ch 4 — Hydrogen

Isotopes of Hydrogen

4.1.2

Isotopes of Hydrogen

Hydrogen has three naturally-occurring isotopes -- atoms with the same one proton (and hence the same atomic number, 1) but different numbers of neutrons:

  • Protium (11H_1^1H, usually just written H) -- the ordinary form, with no neutron at all. It is overwhelmingly the most common isotope, making up 99.985% of natural hydrogen, and it is the only one of the three that contains no neutron.
  • Deuterium (12H_1^2H, symbol D), also called heavy hydrogen, has one proton and one neutron, and constitutes about 0.015% of natural hydrogen.
  • Tritium (13H_1^3H, symbol T) has one proton and two neutrons. It is radioactive and occurs only in extremely small traces -- roughly one atom per 10¹⁸ hydrogen atoms.

Since natural hydrogen is a mixture of all three isotopes, and hydrogen exists as the diatomic molecule, combining two atoms at random from this mixture gives rise to six possible molecular species: H₂, HD, D₂, HT, T₂ and DT. …

Figure 4.1Isotopes of hydrogen

What this figure shows. Three ball-and-stick/space-filling atomic models, one for each isotope, each drawn as a pale green electron-cloud sphere with a small orbiting electron dot and a central coloured nucleus. Protium's nucleus is a single pink/purple sphere (1 proton, 0 neutrons). Deuterium's nucleus pairs one pink proton with one white/grey neutron (1 proton, 1 neutron). Tritium's nucleus shows one pink proton together with two white/grey neutrons (1 proton, 2 neutrons) -- visually sh …

Table 4.1Properties of Hydrogen, Deuterium and Tritium molecules
PropertyProtiumDeuteriumTritium
Atomic Hydrogen
SymbolHDT
Atomic mass (amu)1.0082.0143.016
No. of electrons / protons / neutrons1 / 1 / 01 / 1 / 11 / 1 / 2
Nuclear stabilityStableStableRadioactive (t½ = 12.3 yrs)
Molecular Hydrogen
MoleculeH₂D₂T₂
Abundance (%)99.9850.0156~10⁻¹⁵
Molecular mass (amu)2.0164.0286.032
Melting point (K)13.9618.7320.62
Boiling point (K)20.3923.6725.04
Internuclear distance (pm)74.1474.1474.14
Critical Temperature (K)33.1938.3540.60