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Chemistry · Ch 3 — Periodic Classification of Elements

Moseley's Work and Modern Periodic Law

3.2

Moseley's Work and Modern Periodic Law

In 1913 Henry Moseley bombarded a series of elements with high-energy electrons and studied the characteristic X-rays each element emitted in response. He found a clean linear relationship between the square root of the X-ray frequency and the element's atomic number:

ν=a(Z−b)\sqrt{\nu} = a(Z - b)

where ν\nu is the frequency of the X-rays emitted by the element of atomic number ZZ, and aa and bb are constants with the same value for every element. A plot of ν\sqrt{\nu} against ZZ is a straight line, and this relationship could even be used in reverse -- to determine the atomic number of a newly discovered element from the frequency of the X-rays it emits. …