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Chemistry · Ch 8 — Physical and Chemical Equilibrium

Chemical Equilibrium

8.3

Chemical Equilibrium

Chemical reactions, much like the physical processes above, gradually settle into a state of equilibrium given enough time. Consider a general reversible reaction

A+B⇌C+DA + B \rightleftharpoons C + D

Initially, only A and B are present, so the reaction runs almost entirely in the forward direction, and a few molecules of the products C and D start to appear. As the concentration of C and D builds up, more of these product molecules collide and react with each other in the backward direction, so the rate of the backward reaction keeps rising. At the same time, as A and B are used up, the rate of the forward reaction keeps falling. Eventually the two rates become equal -- and from that p …

Figure 8.3Attainment of equilibrium state for the variation of the rates of forward and backward reactions with time

What this figure shows. Two panels sharing a time axis. The left panel plots reaction rate against time: the forward-reaction curve starts high and falls, the reverse-reaction curve starts at zero and rises, and the two curves meet and become flat (equal rates) once equilibrium is reached. The right panel plots concentration against time: the reactants' concentration curve falls and the products' concentration curve rises, both levelling off to constant values ('no change in amounts') at the same time the two rate curves meet. …