Chemistry · Ch 2 — Quantum Mechanical Model of Atom
Heisenberg's uncertainty principle
Heisenberg's uncertainty principle
If matter genuinely behaves as a wave, there is an unavoidable price to pay: a wave, by its very nature, is spread out rather than located at one exact point, so a particle described by a wave cannot simultaneously have a perfectly sharp position and a perfectly sharp momentum. Werner Heisenberg turned this observation into a precise, quantitative statement now called Heisenberg's uncertainty principle: it is impossible to determine, simultaneously and with unlimited accuracy, both the position and the momentum of a microscopic particle. Formally, if is the uncertainty in position and is the uncertainty in momentum, their product can never be reduced below a fixed minimum:
This is not a statement about the limits of our measuring instruments - it is a fundamental limit built into the wave nature of matter itself. Making smaller (pinning down the position more precisely) necessarily forces to grow larger, and vice versa; the product of the two can shrink no further than .
Why you never notice this in daily life. For any macroscopic object, is such an astronomically tiny number compared to the object's own momentum that the uncertainty is completely undetectable - which is exactly why classical mechanics works perfectly well for footballs, cars and planets. The principle only becomes significant for particles as light as an electron.
Worked illustration: the electron in the first Bohr orbit. Take the electron in hydrogen's first orbit, whose Bohr radius is Å. Suppose its position within that orbit is known to an accuracy of 0.5% of the radius:
Substituting this into Heisenberg's relation (using it as an equality to get the minimum possible uncertainty) and converting :
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What this figure shows. The figure contrasts an 'allowed' orbit with a 'not allowed' one using the electron's de Broglie wave drawn wrapped around the circular path. For orbits labelled n = 3, 4, 5 and 6, an exact whole number of complete wave crests and troughs is drawn fitting perfectly around the circumference, so the wave joins up smoothly on itself - these are marked 'Allowed'. A further circle is drawn where the wave pattern does NOT close up on itself after one full trip around the nucleus (the crests and troughs are out of step where the wave meets its own starting point) and this one is marked 'Not allowed'. The picture is the visual version of the standing-wave argument of the previous section: only orbits whose circumference is an integer multiple of the electron's wavelength can sustain a stable, self …