Skip to content
Question 61 of 66

Q.CH3Br→KCN(A)→H3O+(B)→PCl5(C)CH_3Br \xrightarrow{KCN} (A) \xrightarrow{H_3O^+} (B) \xrightarrow{PCl_5} (C) Product (C) is :

(a) chloro acetic acid
(b) α\alpha-chlorocyano ethanoic acid
(c) acetylchloride
(d) none of these
Tamil Nadu DgeTamil Nadu HSC (DGE) Board 2025MCQ· 1mImportance★★★★★
92% · 61/66 Questions
🔒 Locked · start free trial →

You're viewing a preview — the full solution, concept, methods & PYQ mapping are locked.

Start your 14-day free trial to unlock the full solution →

Methyl bromide is converted stepwise via a nitrile substitution, acid hydrolysis, and finally chlorination of the resulting carboxylic acid's −OH-OH by PCl5PCl_5, ending at acetyl chloride.

Step 1 — formation of A: methyl bromide reacts with potassium cyanide (KCNKCN) in a nucleophilic substitution (SN2S_N2), where the cyanide ion displaces bromide: CH3Br+KCN→CH3CN (A, methyl cyanide / acetonitrile)+KBrCH_3Br + KCN \rightarrow CH_3CN\ (A,\ \text{methyl cyanide / acetonitrile}) + KBr

Step 2 — formation of B: the nitrile A undergoes acid-catalysed hydrolysis (via an amide intermediate) with aqueous acid (H3O+H_3O^+) to give a carboxylic acid: CH3CN+2H2O→H3O+CH3COOH (B, acetic acid)+NH4+CH_3CN + 2H_2O \xrightarrow{H_3O^+} CH_3COOH\ (B,\ \text{acetic acid}) + NH_4^+

…

Unlock everything free for 14 days

  • Full step-by-step solutions
  • Concept-first explanations
  • Methods, shortcuts & mistakes
  • PYQ mapping + timed mock tests

Full access for 14 days. No credit card required.