Chemistry · Ch 5 — Coordination Chemistry
Limitations of Werner's Theory
5.2.1
Limitations of Werner's Theory
The one major gap Werner's otherwise powerful theory left open: even though it explains primary/secondary valence, ionisable versus non-ionisable groups, and the geometry implied by a given secondary valence, it has nothing to say about why coordination compounds are coloured or why they show the magnetic properties they do -- the two properties that Valence Bond Theory and, more …