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Chemistry · Ch 5 — Coordination Chemistry

Naming the Central Metal Atom

5.4.3

Naming the Central Metal Atom

In cationic or neutral complexes the central metal keeps its ordinary element name (e.g. chromium, iron, cobalt); in anionic complexes a suffix '-ate' is added to the metal name instead (chromate, ferrate, cobaltate), and several metals additionally take a shortened Latin-derived stem before the '-ate' suffix. In both cases, the oxidation state of the metal is written immediately after the metal name …

Table 5.4.3-aElement name in cationic vs anionic complexes

Element | Name in cationic/neutral complex | Name in anionic complex

Cr | Chromium | Chromate

Zn | Zinc | Zincate

Al | Aluminum | Aluminate

Fe | Iron | Ferrate

Cu | Copper | Cuprate

Co | Cobalt | Cobaltate

Pb | Lead | Plumbate

Ag | Silver | Argentate …