Chemistry · Ch 5 — Coordination Chemistry
Naming the Central Metal Atom
5.4.3
Naming the Central Metal Atom
In cationic or neutral complexes the central metal keeps its ordinary element name (e.g. chromium, iron, cobalt); in anionic complexes a suffix '-ate' is added to the metal name instead (chromate, ferrate, cobaltate), and several metals additionally take a shortened Latin-derived stem before the '-ate' suffix. In both cases, the oxidation state of the metal is written immediately after the metal name …
Table 5.4.3-aElement name in cationic vs anionic complexes
Element | Name in cationic/neutral complex | Name in anionic complex
Cr | Chromium | Chromate
Zn | Zinc | Zincate
Al | Aluminum | Aluminate
Fe | Iron | Ferrate
Cu | Copper | Cuprate
Co | Cobalt | Cobaltate
Pb | Lead | Plumbate
Ag | Silver | Argentate …