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Chemistry · Ch 8 — Ionic Equilibrium

Buffer Capacity and Buffer Index

8.7.2

Buffer Capacity and Buffer Index

The buffering ability of a solution is quantified by its buffer capacity. Van Slyke introduced the buffer index, β=dBd(pH)\beta = \dfrac{dB}{d(pH)}, where dBdB is the number of gram-equivalents of acid or base added to one litre of buffer solution and d(pH)d(pH) is the resulting change in pH -- i.e. the buffer index is the amount of strong acid or base (in gram-equivalents per litre) needed to change the buffer's pH by exactly one …