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Q.Which will be adsorbed more readily on the surface of charcoal, and why — NH3\text{NH}_3 or O2\text{O}_2?

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Step 1. Among the factors affecting adsorption, the nature of the adsorbate matters: gases that are easily liquefiable — which have comparatively strong van der Waals forces of attraction and high critical temperature — adsorb readily and strongly on charcoal.

Step 2. By contrast, so-called permanent gases, which have low critical temperature and cannot be liquefied easily, adsorb only slowly and weakly.

Step 3. NH3\text{NH}_3 is a polar molecule with significant intermolecular attraction and a relatively high critical temperature (405.5 K), and is classed among the easily-liquefiable gases (alongside SO2\text{SO}_2, HCl and CO2\text{CO}_2) in the chapter's discussion.

Step 4. O2\text{O}_2, by contrast, is a non-polar molecule with weak intermolecular attraction and a very low critical temperature (154.6 K), placing it among the 'permanent gases' (alongside H2\text{H}_2 and N2\text{N}_2) that are hard to liquefy and adsorb only slowly. …

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