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Q.Explain borax bead test with a suitable example.

Telangana TsbieTelangana Board of Intermediate Education (Intermediate 1st Year) 2020Subjective· 4mImportance★★★★★
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Fused borax forms a glassy bead of sodium metaborate + boric anhydride which, when heated with a metal salt, forms a coloured metal metaborate — the bead's colour identifies the metal (e.g., blue for Cu2+).

Principle: Borax, Na2B4O7⋅10H2ONa_2B_4O_7\cdot10H_2O, on strong heating loses its water of crystallisation and then decomposes to give a transparent glassy bead of sodium metaborate and boric anhydride:

Na2B4O7→Δ2NaBO2+B2O3Na_2B_4O_7 \xrightarrow{\Delta} 2NaBO_2 + B_2O_3

Procedure: A small amount of the fused borax bead (formed on a platinum/nichrome wire loop) is touched to a little of the coloured metal salt and reheated in the Bunsen flame. B2O3B_2O_3 reacts with the metal salt to form a metal metaborate, which is often distinctly coloured, e.g.:

B2O3+CuSO4⟶Cu(BO2)2 (blue bead)+SO3B_2O_3 + CuSO_4 \longrightarrow Cu(BO_2)_2\ (\text{blue bead}) + SO_3

Example — Copper(II) sulphate: In the oxidising flame, the bead turns blue (cupric metaborate, Cu(BO2)2Cu(BO_2)_2); in the reducing flame, it turns red/colourless due to reduction to cuprous metaborate.

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