Q.Explain borax bead test with a suitable example.
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Start your 14-day free trial to unlock the full solution →Fused borax forms a glassy bead of sodium metaborate + boric anhydride which, when heated with a metal salt, forms a coloured metal metaborate — the bead's colour identifies the metal (e.g., blue for Cu2+).
Principle: Borax, , on strong heating loses its water of crystallisation and then decomposes to give a transparent glassy bead of sodium metaborate and boric anhydride:
Procedure: A small amount of the fused borax bead (formed on a platinum/nichrome wire loop) is touched to a little of the coloured metal salt and reheated in the Bunsen flame. reacts with the metal salt to form a metal metaborate, which is often distinctly coloured, e.g.:
Example — Copper(II) sulphate: In the oxidising flame, the bead turns blue (cupric metaborate, ); in the reducing flame, it turns red/colourless due to reduction to cuprous metaborate.
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