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Q.Explain borax bead test with a suitable example.

Telangana TsbieTelangana Board of Intermediate Education (Intermediate 1st Year) 2023Subjective· 4mImportance★★★★★
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On heating, borax gives a clear glass bead of B2O3, which reacts with metal salts to form coloured metaborates (e.g. blue for copper), so the bead colour identifies the metal.

Borax bead test:

Borax (Na2B4O7.10H2O) is used to detect coloured metal ions in a salt.

Step 1 - Formation of the bead:

When borax is heated on a loop of platinum wire, it first loses water of crystallisation and swells, and on strong heating it melts to a transparent glassy bead of sodium metaborate and boric anhydride:

Na2B4O7.10H2O -> Na2B4O7 + 10 H2O

Na2B4O7 -> 2 NaBO2 + B2O3 (boric anhydride)

Step 2 - Reaction with the metal salt:

The hot bead is touched to a little of the coloured salt and heated again. The boric anhydride (B2O3) reacts with the metal oxide to form the metaborate of that metal, which has a characteristic colour.

Example - copper salt:

CuSO4 -> CuO (on heating)

CuO + B2O3 -> Cu(BO2)2 (copper metaborate, blue)

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